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Atıksudan Fotokatalitik Yöntemle Boya Giderimi Ve Mineralizasyonu

Year 2020, Volume: 8 Issue: 3, 533 - 539, 30.09.2020
https://doi.org/10.21541/apjes.625338

Abstract

Gelecek yılların en önemli çevresel
sorunlarından biri su kirliliği ve su kıtlığıdır. Bu nedenle boyahaneleriyle
yüksek miktarda su tüketen tekstil endüstrisi gibi üretim tesislerinin
atıksularının ileri düzeyde arıtımı oldukça önemlidir.
Bu atık suların uygun şekilde arıtılmaması insan
ve canlı çevre üzerinde toksik ve kanserojenik etki yapmaktadır. Boyarmaddelerim
karmaşık kompleks yapıları kirlettikleri suyun arıtımını oldukça
zorlaştırmaktadır. Bu nedenle klasik arıtım yöntemleri yetersiz kalmaktadır.
Son zamanlarda, bir ileri arıtım tekniği olan fotokatalitik yöntem boya
giderimi konusunda ilgi çekmeye başlamıştır. Bu çalışmada katyonik boyanın
(metilen mavisi) fotokatalitik yöntemle sulu çözeltiden giderimi ve
mineralizasyonu çalışılmıştır. Deneyler için kullanılan reaktör laboratuvarda
özel olarak tasarlamıştır. Ultraviyole ışık kaynağı olarak UV-C lambalar
kullanılmıştır. Katalizör olarak en yaygın kullanılan iki katalizör olan TiO2
ve ZnO seçilmiştir. Mineralizasyon çalışmasının yanı sıra katalizörlerin
optimum pH’ları, karışım halinde kullanıldığında alınan verim ve tekrar
kullanıma uygunlukları değerlendirilmiş ve kıyaslanmıştır.

References

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  • A. Akyol, H. Yatmaz, and M. Bayramoglu, “Photocatalytic decolorization of Remazol Red RR in aqueous ZnO suspensions”, Applied Catalysis B: Environmental, vol. 54, no. 1, pp. 19–24, 2004.
  • M. Konyar, H. C. Yatmaz, and K. Öztürk, “Sintering temperature effect on photocatalytic efficiencies of ZnO/TiO2 composite plates”, Applied Surface Science, vol. 258, no. 19, pp. 7440–7447, 2012.
  • E. Yassıtepe, H. Yatmaz, C. Öztürk, K. Öztürk, and C. Duran, “Photocatalytic efficiency of ZnO plates in degradation of azo dye solutions”, Journal of Photochemistry and Photobiology A: Chemistry, vol. 198, no. 1, pp. 1–6, 2008.
  • D. Štrbac, C. A. Aggelopoulos, G. Štrbac, M. Dimitropoulos, M. Novaković, T. Ivetić, and S. N. Yannopoulos, “Photocatalytic degradation of Naproxen and methylene blue: Comparison between ZnO, TiO2 and their mixture”, Process Safety and Environmental Protection, vol. 113, pp. 174–183, 2018.
Year 2020, Volume: 8 Issue: 3, 533 - 539, 30.09.2020
https://doi.org/10.21541/apjes.625338

Abstract

References

  • S. R. Couto, “Dye removal by immobilised fungi”, Biotechnology Advances, vol. 27, no. 3, pp. 227–235, 2009..
  • S. Natarajan, H. C. Bajaj, and R. J. Tayade, “Recent advances based on the synergetic effect of adsorption for removal of dyes from waste water using photocatalytic process”, Journal of Environmental Sciences, vol. 65, pp. 201–222, 2018.
  • A. B. D. Santos, F. J. Cervantes, and J. B. V. Lier, “Review paper on current technologies for decolourisation of textile wastewaters: Perspectives for anaerobic biotechnology”, Bioresource Technology, vol. 98, no. 12, pp. 2369–2385, 2007.
  • C. Ram, R. K. Pareek and V. Singh, “Photocatalytic degradation of textile dye by using titanium dioxide nanocatalyst”, International Journal of Theoretical and Applied Sciences, vol. 4, no. 2, pp. 82–88, 2012.
  • A. R. Petcu, C. A. Lazar, E. A. Rogozea, N. L. Olteanu, A. Meghea, and M. Mihaly, “Nonionic microemulsion systems applied for removal of ionic dyes mixtures from textile industry wastewaters”, Separation and Purification Technology, vol. 158, pp. 155–159, 2016.
  • G. Crini and P.-M. Badot, “Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature”, Progress in Polymer Science, vol. 33, no. 4, pp. 399–447, 2008.
  • Y. Zhou, J. Lu, Y. Zhou, and Y. Liu, “Recent advances for dyes removal using novel adsorbents: A review”, Environmental Pollution, vol. 252, pp. 352–365, 2019.
  • H. Pan, J. Feng, G.-X. He, C. E. Cerniglia, and H. Chen, “Evaluation of impact of exposure of Sudan azo dyes and their metabolites on human intestinal bacteria”, Anaerobe, vol. 18, no. 4, pp. 445–453, 2012.
  • V. Gupta and Suhas, “Application of low-cost adsorbents for dye removal – A review”, Journal of Environmental Management, vol. 90, no. 8, pp. 2313–2342, 2009.
  • N. Daneshvar, D. Salari, and A. Khataee, “Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters”, Journal of Photochemistry and Photobiology A: Chemistry, vol. 157, no. 1, pp. 111–116, 2003.
  • D. Georgiou, P. Melidis, A. Aivasidis, and K. Gimouhopoulos, “Degradation of azo-reactive dyes by ultraviolet radiation in the presence of hydrogen peroxide”, Dyes and Pigments, vol. 52, no. 2, pp. 69–78, 2002.
  • M. Moradi, F. Ghanbari, M. Manshouri, and K. A. Angali, “Photocatalytic degradation of azo dye using nano-ZrO2/UV/Persulfate: Response surface modeling and optimization”, Korean Journal of Chemical Engineering, vol. 33, no. 2, pp. 539–546, Dec. 2015.
  • U. Shamraiz, R. A. Hussain, A. Badshah, B. Raza, and S. Saba, “Functional metal sulfides and selenides for the removal of hazardous dyes from Water”, Journal of Photochemistry and Photobiology B: Biology, vol. 159, pp. 33–41, 2016.
  • N. Nandhini, S. Rajeshkumar, and S. Mythili, “The possible mechanism of eco-friendly synthesized nanoparticles on hazardous dyes degradation”, Biocatalysis and Agricultural Biotechnology, vol. 19, p. 101138, 2019.
  • M. Ghaedi, S. Hajjati, Z. Mahmudi, I. Tyagi, S. Agarwal, A. Maity, and V. Gupta, “Modeling of competitive ultrasonic assisted removal of the dyes – Methylene blue and Safranin-O using Fe3O4 nanoparticles”, Chemical Engineering Journal, vol. 268, pp. 28–37, 2015.
  • B. Neppolian, S. Sakthivel, B. Arabindoo, M. Palanichamy, and V. Murugesan, “Degradation of textile dye by solar light using TiO2 and ZnO photocatalysts”, Journal of Environmental Science and Health, Part A, vol. 34, no. 9, pp. 1829–1838, 1999.
  • M. Kaneko and I. Okura, Photocatalysis: science and technology. Tokyo: Kodansha, 2011.
  • R. P. Souza, T. K. Freitas, F. S. Domingues, O. Pezoti, E. Ambrosio, A. M. Ferrari-Lima, and J. C. Garcia, “Photocatalytic activity of TiO2, ZnO and Nb2O5 applied to degradation of textile wastewater”, Journal of Photochemistry and Photobiology A: Chemistry, vol. 329, pp. 9–17, 2016.
  • X. Zhu, C. Yuan, Y. Bao, J. Yang, and Y. Wu, “Photocatalytic degradation of pesticide pyridaben on TiO2 particles”, Journal of Molecular Catalysis A: Chemical, vol. 229, no. 1-2, pp. 95–105, 2005.
  • N. Guettaï and H. A. Amar, “Photocatalytic oxidation of methyl orange in presence of titanium dioxide in aqueous suspension. Part I: Parametric study,” Desalination, vol. 185, no. 1-3, pp. 427–437, 2005.
  • A. Akyol, H. Yatmaz, and M. Bayramoglu, “Photocatalytic decolorization of Remazol Red RR in aqueous ZnO suspensions”, Applied Catalysis B: Environmental, vol. 54, no. 1, pp. 19–24, 2004.
  • M. Konyar, H. C. Yatmaz, and K. Öztürk, “Sintering temperature effect on photocatalytic efficiencies of ZnO/TiO2 composite plates”, Applied Surface Science, vol. 258, no. 19, pp. 7440–7447, 2012.
  • E. Yassıtepe, H. Yatmaz, C. Öztürk, K. Öztürk, and C. Duran, “Photocatalytic efficiency of ZnO plates in degradation of azo dye solutions”, Journal of Photochemistry and Photobiology A: Chemistry, vol. 198, no. 1, pp. 1–6, 2008.
  • D. Štrbac, C. A. Aggelopoulos, G. Štrbac, M. Dimitropoulos, M. Novaković, T. Ivetić, and S. N. Yannopoulos, “Photocatalytic degradation of Naproxen and methylene blue: Comparison between ZnO, TiO2 and their mixture”, Process Safety and Environmental Protection, vol. 113, pp. 174–183, 2018.
There are 24 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Meltem Sarıoğlu Cebeci 0000-0002-3636-0388

Sefa Furkan Selçuk 0000-0002-3700-4377

Publication Date September 30, 2020
Submission Date September 26, 2019
Published in Issue Year 2020 Volume: 8 Issue: 3

Cite

IEEE M. Sarıoğlu Cebeci and S. F. Selçuk, “Atıksudan Fotokatalitik Yöntemle Boya Giderimi Ve Mineralizasyonu”, APJES, vol. 8, no. 3, pp. 533–539, 2020, doi: 10.21541/apjes.625338.