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THE ADSORPTION OF BASIC RED 46 ON THE NATURAL MINERAL LIMESTONE WITH MONTMORILLONITE

Year 2015, Volume: 16 Issue: 2, 303 - 315, 11.11.2015
https://doi.org/10.18038/btd-a.27492

Abstract

The purpose of this study is to investigate the applicability of the natural mineral limestone with montmorillonite as an adsorbent, and the removal of Basic Red 46 (BR 46) which is used textile industry and given to receiving waters with wastewaters.  The optimum environmental conditions in the adsorption of BR 46 on MKT were determined as initial pH 8.0, temperature 25 oC and adsorbent concentration 1.0 g/L; it was observed that the adsorbed amounts increased linearly with concentration (qd=0.8*Co; R2=0.9965) in the studied initial concentration range. Langmuir, Freundlich, Temkin, Dubinin-Radushkevich isotherm models were applied to equilibrium data and it was concluded that the equilibrium data fitted better to Langmuir isotherm model. The maximum BR 46 adsorption capacity of MKT was determined as 169.5 mg/g. Experimental kinetic data fitted to the pseudo second order reaction kinetic, it was concluded that the intraparticle and external diffusion was effective in the studied adsorption process.

References

  • Albadarin, A.B., Mangwandi, C., Al-Muhtaseb, A.A.H., Walker, G.M., Allen, S.J., and Ahmad, M.N. (2012). Kinetic and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent, Chemical Engineering Journal 179, 193-202.
  • Auta, M., and Hameed, B.H. (2013). Acid modified local clay beads as effective low-cost adsorbent for dynamic adsorption of methylene blue, Journal of Industrial and Engineering Chemistry 19.4, 1153-1161.
  • Barreca, S., Orecchio, S., and Pace, A. (2014). The effect of montmorillonite clay in alginate gel beads for polychlorinated biphenyl adsorption: Isothermal and kinetic studies, Applied Clay Science 99, 220-228.
  • Bulut, E., Özacar, M., and Şengil, İ.A. (2008). Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite, Journal of Hazardous Materials 154.1, 613-622.
  • Eloussaief, M., Jarraya, I., and Benzina, M. (2009). Adsorption of copper ions on two clays from Tunisia: pH and temperature effects, Applied Clay Science 46.4, 409-413.
  • Errais, E., Duplay, J., Darragi, F., M'Rabet, I., Aubert, A., Huber, F., and Morvan, G. (2011). Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters, Desalination 275.1, 74-81.
  • Gücek, A., Şener, S., Bilgen, S., and Mazmancı, M.A. (2005). Adsorption and kinetic studies of cationic and anionic dyes on pyrophyllite from aqueous solutions, Journal of Colloid and Interface Science 286.1, 53-60.
  • Gürses, A., Doğar, Ç., Yalçın, M., Açıkyıldız, M., Bayrak, R., and Karaca, S. (2006). The adsorption kinetics of the cationic dye, methylene blue, onto clay, Journal of Hazardous Materials 131.1, 217-228.
  • Hameed, B.H. (2007). Equilibrium and kinetics studies of 2, 4, 6-trichlorophenol adsorption onto activated clay, Colloids and Surfaces A: Physicochemical and Engineering Aspects 307.1, 45-52.
  • Han, R., Zhang, J., Han, P., Wang, Y., Zhao, Z., and Tang, M. (2009). Study of equilibrium, kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite, Chemical Engineering Journal 145.3, 496-504.
  • Karim, A.B., Mounir, B., Hachkar, M., Bakasse, M., and Yaacoubi, A. (2009). Removal of Basic Red 46 dye from aqueous solution by adsorption onto Moroccan clay, Journal of Hazardous Materials 168.1, 304-309.
  • Kluczka, J., Korolewicz, T., Zołotajkin, M., Simka, W., and Raczek, M. (2013). A New Adsorbent for Boron Removal from Aqueous Solutions, Environmental Technology 34, 1369-1376.
  • Koyuncu, H., Yıldız, N., Salgın, U., Köroğlu, F., and Çalımlı, A. (2011). Adsorption of o-, m- and p- Nitrophenols onto Organically Modified Bentonites, Journal of Hazardous Materials 185.2, 1332-1339.
  • Kurup, L. (2012). Evaluation of the Adsorption Capacity of Alkali - Treated Waste Materials for The Adsorption of Sulphamethoxazole, Water Science and Technology 65, 1531 - 1539.
  • Ma, Q., Shen, F., Lu, X., Bao, W., and Ma, H. (2013). Studies on The Adsorption Behavior of Methyl Orange from Dye Wastewater onto Activated Clay, Desalination and Water Treatment 51.19-21, 3700-3709.
  • Sarı, A., Tuzen, M., and Soylak, M. (2007). Adsorption of Pb (II) and Cr (III) from Aqueous Solution on Celtek Clay, Journal of Hazardous Materials 144.1, 41-46.
  • Sarı, A., Tuzen, M., Citak, D., and Soylak, M. (2007). Equilibrium, Kinetic and Thermodynamic Studies of Adsorption of Pb (II) from Aqueous Solution Onto Turkish Kaolinite Clay, Journal of Hazardous Materials 149.2, 283-291.
  • T.C. Çevre ve Şehircilik Bakanlığı, Su Kirliliği Kontrolü Yönetmeliği, Resmi Gazete Tarihi: 31.12.2004, Resmi Gazete Sayısı: 25687.
  • Tahir, S.S., and Rauf, N. (2006). Removal of a Cationic Dye from Aqueous Solutions by Adsorption onto Bentonite Clay, Chemosphere 63.11, 1842-1848.
  • Toor, M., and Jin, B. (2012). Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye, Chemical Engineering Journal 187, 79-88.
  • Uğurlu, M. (2009). Adsorption of A Textile Dye onto Activated Sepiolite, Microporous and Mesoporous Materials 119.1, 276-283.
  • Uzunoğlu D (2014) Levrek Balığı (Dicentrarchus labrax) Pulu ve Ticari Hidroksiapatit ile Acid Blue 121 Boyarmaddesinin Adsorbsiyonu. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Kimya Mühendisliği Ana Bilim Dalı, Yüksek Lisans Tezi.
  • Vimonses, V., Lei, S., Jin, B., Chow, C.W., and Saint, C. (2009). Adsorption of Congo Red by Three Australian Kaolins, Applied Clay Science 43.3, 465-472.
  • Wahab, M.A., Jellali, S., and Jedidi, N. (2010). Ammonium Biosorption onto Sawdust: FTIR Analysis, Kinetics and Adsorption Isotherms Modeling, Bioresource Technology, 101, 5070-5075.  

BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU

Year 2015, Volume: 16 Issue: 2, 303 - 315, 11.11.2015
https://doi.org/10.18038/btd-a.27492

Abstract

Bu çalışmanın amacı, doğada bol bulunabilen kil minerallerinden montmorillonitli kireç taşı (MKT)’nın adsorbent olarak kullanımı ile tekstil endüstrisinde kullanılan ve atık sular ile alıcı sulara verilen Basic Red 46 boyar maddesi (BR 46)’nin giderimini araştırmaktır. BR 46’nin MKT’na adsorbsiyonunda optimum ortam koşulları başlangıç pH’sı 8.0, sıcaklık 25 oC ve adsorbent derişimi 1.0 g/L olarak belirlenmiş; çalışılan başlangıç BR 46 derişimi aralığında, adsorplanan miktarların derişim ile doğrusal olarak arttığı (qd=0.8*Co; R2=0.9965) gözlenmiştir. Deneysel denge verilerine Langmuir, Freundlich, Temkin ve Dubinin-Radushkevich izoterm modelleri uygulanmış; denge verilerinin Langmuir izoterm modeline daha iyi uyduğu sonucuna varılmıştır. MKT’nın BR 46’ni maksimum tek tabaka adsorplama kapasitesi 169.5 mg/g olarak belirlenmiştir. Deneysel kinetik veriler yalancı ikinci mertebe kinetik modeline uyum göstermiş; çalışılan adsorpsiyon prosesinde tanecik içi ve dışı difüzyonun etkili olduğu sonucuna varılmıştır. Entalpi, entropi ve Gibbs serbest enerji değişimi gibi termodinamik parametrelere göre çalışılan adsorpsiyon prosesinin ekzotermik ve istemli olduğu belirlenmiştir. MKT’nın adsorpsiyon öncesi ve sonrası FTIR, SEM ve EDX analizleri ile karakterizasyon çalışmaları gerçekleştirilmiştir. 

References

  • Albadarin, A.B., Mangwandi, C., Al-Muhtaseb, A.A.H., Walker, G.M., Allen, S.J., and Ahmad, M.N. (2012). Kinetic and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent, Chemical Engineering Journal 179, 193-202.
  • Auta, M., and Hameed, B.H. (2013). Acid modified local clay beads as effective low-cost adsorbent for dynamic adsorption of methylene blue, Journal of Industrial and Engineering Chemistry 19.4, 1153-1161.
  • Barreca, S., Orecchio, S., and Pace, A. (2014). The effect of montmorillonite clay in alginate gel beads for polychlorinated biphenyl adsorption: Isothermal and kinetic studies, Applied Clay Science 99, 220-228.
  • Bulut, E., Özacar, M., and Şengil, İ.A. (2008). Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite, Journal of Hazardous Materials 154.1, 613-622.
  • Eloussaief, M., Jarraya, I., and Benzina, M. (2009). Adsorption of copper ions on two clays from Tunisia: pH and temperature effects, Applied Clay Science 46.4, 409-413.
  • Errais, E., Duplay, J., Darragi, F., M'Rabet, I., Aubert, A., Huber, F., and Morvan, G. (2011). Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters, Desalination 275.1, 74-81.
  • Gücek, A., Şener, S., Bilgen, S., and Mazmancı, M.A. (2005). Adsorption and kinetic studies of cationic and anionic dyes on pyrophyllite from aqueous solutions, Journal of Colloid and Interface Science 286.1, 53-60.
  • Gürses, A., Doğar, Ç., Yalçın, M., Açıkyıldız, M., Bayrak, R., and Karaca, S. (2006). The adsorption kinetics of the cationic dye, methylene blue, onto clay, Journal of Hazardous Materials 131.1, 217-228.
  • Hameed, B.H. (2007). Equilibrium and kinetics studies of 2, 4, 6-trichlorophenol adsorption onto activated clay, Colloids and Surfaces A: Physicochemical and Engineering Aspects 307.1, 45-52.
  • Han, R., Zhang, J., Han, P., Wang, Y., Zhao, Z., and Tang, M. (2009). Study of equilibrium, kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite, Chemical Engineering Journal 145.3, 496-504.
  • Karim, A.B., Mounir, B., Hachkar, M., Bakasse, M., and Yaacoubi, A. (2009). Removal of Basic Red 46 dye from aqueous solution by adsorption onto Moroccan clay, Journal of Hazardous Materials 168.1, 304-309.
  • Kluczka, J., Korolewicz, T., Zołotajkin, M., Simka, W., and Raczek, M. (2013). A New Adsorbent for Boron Removal from Aqueous Solutions, Environmental Technology 34, 1369-1376.
  • Koyuncu, H., Yıldız, N., Salgın, U., Köroğlu, F., and Çalımlı, A. (2011). Adsorption of o-, m- and p- Nitrophenols onto Organically Modified Bentonites, Journal of Hazardous Materials 185.2, 1332-1339.
  • Kurup, L. (2012). Evaluation of the Adsorption Capacity of Alkali - Treated Waste Materials for The Adsorption of Sulphamethoxazole, Water Science and Technology 65, 1531 - 1539.
  • Ma, Q., Shen, F., Lu, X., Bao, W., and Ma, H. (2013). Studies on The Adsorption Behavior of Methyl Orange from Dye Wastewater onto Activated Clay, Desalination and Water Treatment 51.19-21, 3700-3709.
  • Sarı, A., Tuzen, M., and Soylak, M. (2007). Adsorption of Pb (II) and Cr (III) from Aqueous Solution on Celtek Clay, Journal of Hazardous Materials 144.1, 41-46.
  • Sarı, A., Tuzen, M., Citak, D., and Soylak, M. (2007). Equilibrium, Kinetic and Thermodynamic Studies of Adsorption of Pb (II) from Aqueous Solution Onto Turkish Kaolinite Clay, Journal of Hazardous Materials 149.2, 283-291.
  • T.C. Çevre ve Şehircilik Bakanlığı, Su Kirliliği Kontrolü Yönetmeliği, Resmi Gazete Tarihi: 31.12.2004, Resmi Gazete Sayısı: 25687.
  • Tahir, S.S., and Rauf, N. (2006). Removal of a Cationic Dye from Aqueous Solutions by Adsorption onto Bentonite Clay, Chemosphere 63.11, 1842-1848.
  • Toor, M., and Jin, B. (2012). Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye, Chemical Engineering Journal 187, 79-88.
  • Uğurlu, M. (2009). Adsorption of A Textile Dye onto Activated Sepiolite, Microporous and Mesoporous Materials 119.1, 276-283.
  • Uzunoğlu D (2014) Levrek Balığı (Dicentrarchus labrax) Pulu ve Ticari Hidroksiapatit ile Acid Blue 121 Boyarmaddesinin Adsorbsiyonu. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Kimya Mühendisliği Ana Bilim Dalı, Yüksek Lisans Tezi.
  • Vimonses, V., Lei, S., Jin, B., Chow, C.W., and Saint, C. (2009). Adsorption of Congo Red by Three Australian Kaolins, Applied Clay Science 43.3, 465-472.
  • Wahab, M.A., Jellali, S., and Jedidi, N. (2010). Ammonium Biosorption onto Sawdust: FTIR Analysis, Kinetics and Adsorption Isotherms Modeling, Bioresource Technology, 101, 5070-5075.  
There are 24 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Deniz Uzunoğlu

Ayla Özer This is me

Zeynep Özdemir This is me

Publication Date November 11, 2015
Published in Issue Year 2015 Volume: 16 Issue: 2

Cite

APA Uzunoğlu, D., Özer, A., & Özdemir, Z. (2015). BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(2), 303-315. https://doi.org/10.18038/btd-a.27492
AMA Uzunoğlu D, Özer A, Özdemir Z. BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU. AUJST-A. November 2015;16(2):303-315. doi:10.18038/btd-a.27492
Chicago Uzunoğlu, Deniz, Ayla Özer, and Zeynep Özdemir. “BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16, no. 2 (November 2015): 303-15. https://doi.org/10.18038/btd-a.27492.
EndNote Uzunoğlu D, Özer A, Özdemir Z (November 1, 2015) BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 2 303–315.
IEEE D. Uzunoğlu, A. Özer, and Z. Özdemir, “BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU”, AUJST-A, vol. 16, no. 2, pp. 303–315, 2015, doi: 10.18038/btd-a.27492.
ISNAD Uzunoğlu, Deniz et al. “BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/2 (November 2015), 303-315. https://doi.org/10.18038/btd-a.27492.
JAMA Uzunoğlu D, Özer A, Özdemir Z. BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU. AUJST-A. 2015;16:303–315.
MLA Uzunoğlu, Deniz et al. “BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 2, 2015, pp. 303-15, doi:10.18038/btd-a.27492.
Vancouver Uzunoğlu D, Özer A, Özdemir Z. BASIC RED 46 BOYAR MADDESİNİN MONTMORİLLONİTLİ KİREÇ TAŞINA ADSORBSİYONU. AUJST-A. 2015;16(2):303-15.