Research Article
BibTex RIS Cite

Ihlamur Bitkisinin (Tilia cordata) Katı-Sıvı Ekstraksiyonunda Toplam Fenolik Madde Kinetiğinin Matematiksel Modellenmesi

Year 2018, Volume: 22 Issue: 1, 12 - 20, 27.03.2018
https://doi.org/10.29050/harranziraat.315709

Abstract

Ihlamur
çayı, en etkili doğal ilaçlardan biridir ve yüzyıllardır kullanılmaktadır.
Düzenli olarak tüketildiğinde çeşitli sağlık sorunlarının üstesinden
gelinmesinde az veya çok etki gösterebilir. Tilia (Tiliaceae)
cinsi bitkilerin gösterdiği antioksidan ve antimikrobiyal aktivite gibi
işlevsel özellikler flavonoidler de dahil olmak üzere polifenolik bileşiklerle
ilişkilidir. Bu yüzden toplam fenolik bileşiklerce zengin olan ıhlamurun
demlenmesinde süre-sıcaklık ilişkisi önemlidir. Bu çalışmada 5 farklı
sıcaklıkta (60, 70, 80, 90 ve 100 °C) demlenen ıhlamur bitkisinin katı-sıvı
ektraksiyonunda polifenollerin sıvı faza geçme süreleri incelenmiştir. Toplam
fenolik bileşiklerin katı-sıvı ekstraksiyonunun Matematiksel modellemesinde
Fick yasasının uyarlanmış hali kullanılmıştır. Ihlamur bitkisinin (Tilia cordata) çayı geleneksel yöntemle
hazırlanmıştır. Kuru ıhlamur yaprakları öğütülerek elekten geçirilmiştir. Çelik
demleme süzgecine konulan öğütülmüş ıhlamur yaprakları deiyonize su içerisine
daldırılmıştır. Homojenize ıhlamur ekstraksiyonu için sabit ve düşük hızda
dönen magnetik karıştırıcı kullanılmıştır. Farklı zaman aralıklarında ekstrakt
örneği alınmış ve filtre edilmiştir. Ekstraksiyon işlemine her bir sıcaklıktaki
ıhlamur konsantrasyonu değişmeyene kadar devam edilmiştir. Örneklerin toplam
fenolik bileşikleri spektrofotometrik yöntemle belirlenmiş ve gallik asit
eşdeğerleri (GAE) mg ml-1 olarak
ifade edilmiştir. Katı-sıvı faz ıhlamur ekstraksiyon uygulama sonrası bütün
sıcaklıklardaki toplam fenolik madde miktarlarının denge konsantrasyonları
40.5-43 mg l-1 arasında
değiştiği belirlenmiştir. Toplam fenolik maddelerin %99.9’ unun sıvı faza
transfer süreleri ise yaklaşık 2078-57 dakika arasındadır. En düşük hız sabiti
60°C’de, en yüksek ise 100 °C’de bulunurken 100 °C’deki hız sabitinin diğer
sıcaklıklara göre 2 ile 36 kat daha büyük olduğu gözlemlenmiştir. Ayrıca
aktivasyon enerjisi 0.549 kJ g-1 olarak
belirlenmiştir.

References

  • Atoui, A.K., Mansouri, A., Boskou, G., Kefalas, P., 2005. Tea and Herbal Infusions: Their Antioxidant Activity and Phenolic Profile. Food Chemistry, 89: 27-36.
  • Baser, K., Kürkçüoğlu, M., Özek, T., 1999. The Composition of Essential Oils From Tilia L. Species Growing in Turkey. Journal of Essential Oil Research, 11: 369-374. Baytop, T., 1999. Türkiye’de Bitkiler ile Tedavi: Geçmişte ve Bugün (ilaveli 2. Baskı). Nobel Tıp Kitapları, İstanbul, 480s.
  • Cacace, J. E., Mazza, G., 2003. Mass Transfer Process During Extraction of Phenolic Compounds from Milled Berries. Journal of Food Engineering, 59 (4): 379-389.
  • Chan, C.H., Yusoff, R., Ngoh, G.C., 2014. Modeling and Kinetics Study of Conventional and Assisted Batch Solvent Extraction. Chemical Engineering Research and Design, 9 (2): 1169-1186.
  • Cisse, M., Bohuon, P., Sambe, F., Kane, C., Sakho, M., Dornier, M., 2012. Aqueous Extraction of Anthocyanins from Hibiscus sabdariffa: Experimental Kinetics and Modeling. Journal of Food Engineering, 109: 16-21.
  • Crossley, J.I., Aguilera, J.M., 2001. Modeling The Effect of Microstructure on Food Extraction. Journal of Food Process Engineering, 24: 161–177.
  • Daniel, A., 1998. Preparation lavante a usage capillaire. French Patent, FR2752730. Franco, D., Sineiro, J., Pinelo, M., Núñez,M.J., 2007. Ethanolic Extraction of Rosa rubiginosa Soluble Substances: Oil Solubility Equilibria and Kinetic Studies. Journal of Food Engineering, 79: 150-157.
  • Geankoplis, C.J., 2003. Transport Processes and Separation Process Princeples: Includes Unite Operations (4. Baskı). Prentice Hall. New Jersey, 410-490.
  • Gujar, J.G., Wagh, S.J., Gaikar, V.G., 2010. Experimental and Modeling Studies on Microwave-assisted Extraction of Thymol From Seeds of Trachyspermum ammi (TA). Separation and Purification Technology, 70 (3): 257–264.
  • Haldar, S., Majumdar, G.C., Mishra, H.N., 2015. Modeling the Kinetics of Extracting Oleoresin from Dried Turmeric (Curcuma longa L.) Rhizome Using Acetone as Solvent. Journal of Food Engineering, 146: 116-121.
  • Harouna-Oumarou, H.A., Fauduet, H., Porte, C., Ho, Y., 2007. Comparison of Kinetic Models for the Aqueous Solid-Liquid Extraction of Tilia Sapwood in a Continuous Stirred Tank Reactor. Chemical Engineering Communications, 194: 537-552.
  • Ivanova, D., Gerova, D., Chervenkov, T., Yankova, T., 2005. Polyphenols and Antioxidant Capacity of Bulgarian Medicinal Plants. Journal of Ethnopharmacology, 96: 145-150.
  • Lin, C., Xia, G., Liu, S., 2017. Modelling and Comparison of Extraction Kinetics of 8 Catechins, Gallic Acid and Caffeine from Representative White Teas. LWT – Food Science and Technology, 83: 1-9.
  • Matsuda, H., Ninomiya, K., Shimoda, H., Yoshikawa, M., 2002. Hepatoprotective Principles from the Flowers of Tilia argentea (Linden): Structure Requirements of Tiliroside and Mechanisms of Action. Bioorganic & Medicinal Chemistry, 10: 707-712.
  • Mentell, C. ve Rodriguez, M., 2002. Semi-Batch Extraction of Anthociyanins from Red Grape Pomace in Packed Beds: Experimental Results and Process Modelling. Chemical Engieering Science, 57: 3831-3838.
  • Perez, E.E., Carelli, A.A., Crapiste, G.H., 2011. Temperature-dependent Diffusion Coefficient of Oil from Different Sunflower Seeds During Extraction with Hexane. Journal of Food Engineering, 105: 180–185
  • Perry, R., Green, D.W., Maloney, J.O., 1997. Perry’s Chemical Engineers’ Handbook (7. Baskı). McGraw-Hill, New York, 2640s. Pinelo, M., Arnous, A., Meyer, A.S., 2006. Upgrading of Grape Skins: Significance of Plant Cell-wall Structural Components and Extraction Techniques for Phenol Release. Trends in Food Science & Technology, 17 (11): 579-590.
  • Rakotondramasy-Rabesiaka, L., Havet, J.L., Porte, C., Fauduet, H., 2009. Solid–liquid Extraction of Protopine from Fumaria officinalis L. – Kinetic Modelling of Influential Parameters. Industrial Crops ans Products, 29 (2–3): 516–523.
  • Romdhane, M., Gourdon, C., 2002. Investigation in Solid-liquid Extraction: Influence of Ultrasound. Chemical Engineering Journal, 87: 11-19.
  • Schmidgall, J., Schnetz, E., Hensel, A., 2000. Evidence for Bioadhesive Effects of Polysaccharides and Polysaccharide-containing Herbs in an ex vivo Bioadhesion Assay on Buccal Membranes. Planta Medica, 66: 48-53.
  • So, G.C., Macdonald, D.G., 1986. Kinetics of Oil Extraction from Canola (Rapeseed). The Canadian Journal of Chemical Engineering, 64: 80-86.
  • Toker, G., Aslan, M., Yeşilada, E., Memişoğlu, M., Ito, S., 2001. Comparative Evaluation of the Flavonoid Content in Officinal Tiliae flos and Turkish Lime Species for Quality Assessment. Journal of Pharmaceutical and Biomedical Analysis, 26: 111-121.
  • Toker, G., Küpeli, E., Memişoğlu, M., Yeşilada, E., 2004. Flavonoids with Anti-nociceptive and Anti-inflammatory Activities from the Leaves of Tilia argentea (silver linden). Journal of Ethnopharmacology, 95 (2-3): 393-397.
  • Tosun, G., Bozan, B., 2010. Üzüm Çekirdeğinden Fenolik Bileşiklerin Ekstraksiyonu ve Kütle Transfer Parametrelerinin İncelenmesi. 9. Ulusal Kimya Mühendisliği Kongresi, 22-25 Haziran, Ankara.
  • Tsibranska, I., Tylkowski, B., Kochanov, R., Alipieva, K., 2011. Extraction of Biologically Active Compounds From Sideritis ssp. L. Food Bioproducts Processing, 89 (4): 273–280.
  • Usal, G., Özde A.A., 2001. Türkiye’nin Tıbbi Bitkiler İhracat Potansiyeli. Gıda, 10: 78–79
  • Viola, H., Wolfman, C., Levi de Stein, M., Wasowski, C., 1994. Isolation of Pharmacologically Active Benzodiazepine Receptor Ligands from Tilia tomentosa (Tiliaceae). Journal of Ethnopharmacology, 44: 47-53.
  • Yıldırım, A., Mavi, A., Oktay, M., Kara, A.A., Algur, O.F., Bilaloğlu, V., 2000. Comparison of Antioxidant and Antimicrobial Activities of Tilia (Tilia argenta Desf Ex DC), Sage (Salvia triloba L.) and Black Tea (Camellia sinensis) Extracts. Journal of Agricultural and Food Chemistry, 48: 5030-5034.
Year 2018, Volume: 22 Issue: 1, 12 - 20, 27.03.2018
https://doi.org/10.29050/harranziraat.315709

Abstract

References

  • Atoui, A.K., Mansouri, A., Boskou, G., Kefalas, P., 2005. Tea and Herbal Infusions: Their Antioxidant Activity and Phenolic Profile. Food Chemistry, 89: 27-36.
  • Baser, K., Kürkçüoğlu, M., Özek, T., 1999. The Composition of Essential Oils From Tilia L. Species Growing in Turkey. Journal of Essential Oil Research, 11: 369-374. Baytop, T., 1999. Türkiye’de Bitkiler ile Tedavi: Geçmişte ve Bugün (ilaveli 2. Baskı). Nobel Tıp Kitapları, İstanbul, 480s.
  • Cacace, J. E., Mazza, G., 2003. Mass Transfer Process During Extraction of Phenolic Compounds from Milled Berries. Journal of Food Engineering, 59 (4): 379-389.
  • Chan, C.H., Yusoff, R., Ngoh, G.C., 2014. Modeling and Kinetics Study of Conventional and Assisted Batch Solvent Extraction. Chemical Engineering Research and Design, 9 (2): 1169-1186.
  • Cisse, M., Bohuon, P., Sambe, F., Kane, C., Sakho, M., Dornier, M., 2012. Aqueous Extraction of Anthocyanins from Hibiscus sabdariffa: Experimental Kinetics and Modeling. Journal of Food Engineering, 109: 16-21.
  • Crossley, J.I., Aguilera, J.M., 2001. Modeling The Effect of Microstructure on Food Extraction. Journal of Food Process Engineering, 24: 161–177.
  • Daniel, A., 1998. Preparation lavante a usage capillaire. French Patent, FR2752730. Franco, D., Sineiro, J., Pinelo, M., Núñez,M.J., 2007. Ethanolic Extraction of Rosa rubiginosa Soluble Substances: Oil Solubility Equilibria and Kinetic Studies. Journal of Food Engineering, 79: 150-157.
  • Geankoplis, C.J., 2003. Transport Processes and Separation Process Princeples: Includes Unite Operations (4. Baskı). Prentice Hall. New Jersey, 410-490.
  • Gujar, J.G., Wagh, S.J., Gaikar, V.G., 2010. Experimental and Modeling Studies on Microwave-assisted Extraction of Thymol From Seeds of Trachyspermum ammi (TA). Separation and Purification Technology, 70 (3): 257–264.
  • Haldar, S., Majumdar, G.C., Mishra, H.N., 2015. Modeling the Kinetics of Extracting Oleoresin from Dried Turmeric (Curcuma longa L.) Rhizome Using Acetone as Solvent. Journal of Food Engineering, 146: 116-121.
  • Harouna-Oumarou, H.A., Fauduet, H., Porte, C., Ho, Y., 2007. Comparison of Kinetic Models for the Aqueous Solid-Liquid Extraction of Tilia Sapwood in a Continuous Stirred Tank Reactor. Chemical Engineering Communications, 194: 537-552.
  • Ivanova, D., Gerova, D., Chervenkov, T., Yankova, T., 2005. Polyphenols and Antioxidant Capacity of Bulgarian Medicinal Plants. Journal of Ethnopharmacology, 96: 145-150.
  • Lin, C., Xia, G., Liu, S., 2017. Modelling and Comparison of Extraction Kinetics of 8 Catechins, Gallic Acid and Caffeine from Representative White Teas. LWT – Food Science and Technology, 83: 1-9.
  • Matsuda, H., Ninomiya, K., Shimoda, H., Yoshikawa, M., 2002. Hepatoprotective Principles from the Flowers of Tilia argentea (Linden): Structure Requirements of Tiliroside and Mechanisms of Action. Bioorganic & Medicinal Chemistry, 10: 707-712.
  • Mentell, C. ve Rodriguez, M., 2002. Semi-Batch Extraction of Anthociyanins from Red Grape Pomace in Packed Beds: Experimental Results and Process Modelling. Chemical Engieering Science, 57: 3831-3838.
  • Perez, E.E., Carelli, A.A., Crapiste, G.H., 2011. Temperature-dependent Diffusion Coefficient of Oil from Different Sunflower Seeds During Extraction with Hexane. Journal of Food Engineering, 105: 180–185
  • Perry, R., Green, D.W., Maloney, J.O., 1997. Perry’s Chemical Engineers’ Handbook (7. Baskı). McGraw-Hill, New York, 2640s. Pinelo, M., Arnous, A., Meyer, A.S., 2006. Upgrading of Grape Skins: Significance of Plant Cell-wall Structural Components and Extraction Techniques for Phenol Release. Trends in Food Science & Technology, 17 (11): 579-590.
  • Rakotondramasy-Rabesiaka, L., Havet, J.L., Porte, C., Fauduet, H., 2009. Solid–liquid Extraction of Protopine from Fumaria officinalis L. – Kinetic Modelling of Influential Parameters. Industrial Crops ans Products, 29 (2–3): 516–523.
  • Romdhane, M., Gourdon, C., 2002. Investigation in Solid-liquid Extraction: Influence of Ultrasound. Chemical Engineering Journal, 87: 11-19.
  • Schmidgall, J., Schnetz, E., Hensel, A., 2000. Evidence for Bioadhesive Effects of Polysaccharides and Polysaccharide-containing Herbs in an ex vivo Bioadhesion Assay on Buccal Membranes. Planta Medica, 66: 48-53.
  • So, G.C., Macdonald, D.G., 1986. Kinetics of Oil Extraction from Canola (Rapeseed). The Canadian Journal of Chemical Engineering, 64: 80-86.
  • Toker, G., Aslan, M., Yeşilada, E., Memişoğlu, M., Ito, S., 2001. Comparative Evaluation of the Flavonoid Content in Officinal Tiliae flos and Turkish Lime Species for Quality Assessment. Journal of Pharmaceutical and Biomedical Analysis, 26: 111-121.
  • Toker, G., Küpeli, E., Memişoğlu, M., Yeşilada, E., 2004. Flavonoids with Anti-nociceptive and Anti-inflammatory Activities from the Leaves of Tilia argentea (silver linden). Journal of Ethnopharmacology, 95 (2-3): 393-397.
  • Tosun, G., Bozan, B., 2010. Üzüm Çekirdeğinden Fenolik Bileşiklerin Ekstraksiyonu ve Kütle Transfer Parametrelerinin İncelenmesi. 9. Ulusal Kimya Mühendisliği Kongresi, 22-25 Haziran, Ankara.
  • Tsibranska, I., Tylkowski, B., Kochanov, R., Alipieva, K., 2011. Extraction of Biologically Active Compounds From Sideritis ssp. L. Food Bioproducts Processing, 89 (4): 273–280.
  • Usal, G., Özde A.A., 2001. Türkiye’nin Tıbbi Bitkiler İhracat Potansiyeli. Gıda, 10: 78–79
  • Viola, H., Wolfman, C., Levi de Stein, M., Wasowski, C., 1994. Isolation of Pharmacologically Active Benzodiazepine Receptor Ligands from Tilia tomentosa (Tiliaceae). Journal of Ethnopharmacology, 44: 47-53.
  • Yıldırım, A., Mavi, A., Oktay, M., Kara, A.A., Algur, O.F., Bilaloğlu, V., 2000. Comparison of Antioxidant and Antimicrobial Activities of Tilia (Tilia argenta Desf Ex DC), Sage (Salvia triloba L.) and Black Tea (Camellia sinensis) Extracts. Journal of Agricultural and Food Chemistry, 48: 5030-5034.
There are 28 citations in total.

Details

Primary Language Turkish
Subjects Agricultural Engineering
Journal Section Araştırma Makaleleri
Authors

Ahmet Levent İnanç 0000-0002-7363-5096

Doğanay Yüksel

Publication Date March 27, 2018
Submission Date May 24, 2017
Published in Issue Year 2018 Volume: 22 Issue: 1

Cite

APA İnanç, A. L., & Yüksel, D. (2018). Ihlamur Bitkisinin (Tilia cordata) Katı-Sıvı Ekstraksiyonunda Toplam Fenolik Madde Kinetiğinin Matematiksel Modellenmesi. Harran Tarım Ve Gıda Bilimleri Dergisi, 22(1), 12-20. https://doi.org/10.29050/harranziraat.315709

Indexing and Abstracting 

13435  19617 13436 13440 13441 13442 13443

13445 13447 13449 13464 13466


10749  Harran Journal of Agricultural and Food Science is licensed under Creative Commons 4.0 International License.