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A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions

Year 2023, Volume: 7 Issue: 2, 180 - 187, 31.12.2023

İlyas Yıldız Ramazan Erenler Mehmet Hakkı Alma Ömer Işıldak Tarık Aral

https://doi.org/10.32571/ijct.1374226

Abstract

(1S, 2S, N1, N2) -N1, N2 bis ((2-metil-1H-indol-3-il) metilen) sikloheksan-1,2 -diamin (iyonofor) bileşik bazlı demir (III) iyonuna seçici yeni bir katı hal kontak potansiyometrik membran elektrodu geliştirildi. Öncelikle geliştirilen elektrotun minimum membran bileşimi belirlendi. Ayrıca elektrotun seçicilik, tespit limiti, pH aralığı, tepki süresi, konsantrasyon aralığı ve potansiyel kararlılık gibi potansiyometrik performans özellikleri de araştırıldı. Elde edilen sonuçlar, elektrotun 43.00 ± 5 mV/decade Nernstian temki değerine ve geniş doğrusal konsantrasyon aralığında (1.0×10−6-1,0×10-2 M) çok düşük tayın sınırına (6.5×10-6 M) sahip olduğunu gösterdi. Elektrotun potansiyometrik pH tepkisi 2-11 gibi geniş bir aralıkta olup çözeltilere verdiği süre <20 s kadar kısadır. Ayrıca elde edilen elektrot, çeşitli katyonlar içeren ve demir (III) iyonlarını içeren bir çözelti içerisinde demir (III) iyonlarına karşı çok iyi bir seçicilik sergilemiştir. Geliştirilen elektrot, atık su ve meyve sularındaki demir (III)'ün hızlı, düşük maliyetli ve yerinde analizi için potansiyometrik yöntemle başarıyla uygulandı.

Keywords

PVC membrane potentiometric sensor iron (III)-selective indole derivative

References

  • Erenler, R.; Cakmak, O. J Chem Res 2004, (8), 566-569.
  • Erenler, R.; Biellmann, J. F. Tetrahedron Lett 2005, 46 (34), 5683-5685.
  • Cakmak, O.; Erenler, R.; Tutar, A.; Celik, N. J Org Chem 2006, 71 (5), 1795-1801.
  • Erenler, R.; Demirtas, I.; Buyukkidan, B.; Cakmak, O. J Chem Res 2006, (12), 753-757.
  • Erenler, R. Asian J Chem 2007, 19 (3), 2207-2210.
  • Erenler, R.; Biellmann, J. F. J Chin Chem Soc 2007, 54 (1), 103-108.
  • Erenler, R.; Uno, M.; Goud, T. V.; Biellmanna, J. F. J Chem Res 2009, 2009 (7), 459-464.
  • Tutar, A.; Erenler, R. J Chem Soc Pakistan 2012, 34 (6), 1526-1530.
  • Varshney, A.; Kumar, A. Journal of Chemical Sciences 2022, 134 (4), ID 124.
  • Handy, D. E.; Loscalzo, J. Antioxidants & redox signaling 2012, 16 (11), 1323-1367.
  • Rout, G. R.; Sahoo, S. Reviews in Agricultural Science 2015, 3, 1-24.
  • Bera, R. K.; Baral, M.; Sahoo, S. K.; Kanungo, B. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2015, 134, 165-172.
  • Zhu, C.; Lu, W.; He, Y.; Ke, S.; Wu, H.; Zhang, L. Acta Geochimica 2018, 37 (5), 691-700.
  • Kaasalainen, H.; Stefánsson, A.; Druschel, G. K. International Journal of Environmental Analytical Chemistry 2016, 96 (11), 1074-1090.
  • Xia, L.; Wu, Y.; Jiang, Z.; Li, S.; Hu, B. Intern J Environ Anal Chem 2003, 83 (11), 953-962.
  • Kizilkaya, H.; Dag, B.; Aral, T.; Genc, N.; Erenler, R. Journal of the Chinese Chemical Society 2020, 67 (9), 1696-1701.
  • Zamani, H. A.; Faridbod, F. Journal of Analytical Chemistry 2014, 69 (11), 1073-1078.
  • Umezawa, Y.; Bühlmann, P.; Umezawa, K.; Tohda, K.; Amemiya, S. Pure and Applied Chemistry 2000, 72 (10), 1851-2082.
  • Zamani, H. A.; Ganjali, M. R.; Behmadi, H.; Behnajady, M. A. Materials Science and Engineering: C 2009, 29 (5), 1535-1539.
  • Masrournia, M.; Zamani, H. A.; Mirrashid, H. A.; Ganjali, M. R.; Faridbod, F. Materials Science and Engineering: C 2011, 31 (3), 574-578.
  • Mizani, F.; Ganjali, M.; Faridbod, F.; Esmaeilnia, S. Int J Electrochem Sci 2013, 8, 10473-10486.
  • Ozer, T.; Isildak, I. Int J Electrochem Sci 2018, 13, 11375-11387.
  • Yari, A.; Bagheri, M.; Ghazizadeh, M. Int J Electrochem Sci 2016, 11, 6597-6608.
  • Gupta, V. K.; Jain, A.; Agarwal, S.; Maheshwari, G. Talanta 2007, 71 (5), 1964-1968.

Year 2023, Volume: 7 Issue: 2, 180 - 187, 31.12.2023

İlyas Yıldız Ramazan Erenler Mehmet Hakkı Alma Ömer Işıldak Tarık Aral

https://doi.org/10.32571/ijct.1374226

Abstract

References

  • Erenler, R.; Cakmak, O. J Chem Res 2004, (8), 566-569.
  • Erenler, R.; Biellmann, J. F. Tetrahedron Lett 2005, 46 (34), 5683-5685.
  • Cakmak, O.; Erenler, R.; Tutar, A.; Celik, N. J Org Chem 2006, 71 (5), 1795-1801.
  • Erenler, R.; Demirtas, I.; Buyukkidan, B.; Cakmak, O. J Chem Res 2006, (12), 753-757.
  • Erenler, R. Asian J Chem 2007, 19 (3), 2207-2210.
  • Erenler, R.; Biellmann, J. F. J Chin Chem Soc 2007, 54 (1), 103-108.
  • Erenler, R.; Uno, M.; Goud, T. V.; Biellmanna, J. F. J Chem Res 2009, 2009 (7), 459-464.
  • Tutar, A.; Erenler, R. J Chem Soc Pakistan 2012, 34 (6), 1526-1530.
  • Varshney, A.; Kumar, A. Journal of Chemical Sciences 2022, 134 (4), ID 124.
  • Handy, D. E.; Loscalzo, J. Antioxidants & redox signaling 2012, 16 (11), 1323-1367.
  • Rout, G. R.; Sahoo, S. Reviews in Agricultural Science 2015, 3, 1-24.
  • Bera, R. K.; Baral, M.; Sahoo, S. K.; Kanungo, B. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2015, 134, 165-172.
  • Zhu, C.; Lu, W.; He, Y.; Ke, S.; Wu, H.; Zhang, L. Acta Geochimica 2018, 37 (5), 691-700.
  • Kaasalainen, H.; Stefánsson, A.; Druschel, G. K. International Journal of Environmental Analytical Chemistry 2016, 96 (11), 1074-1090.
  • Xia, L.; Wu, Y.; Jiang, Z.; Li, S.; Hu, B. Intern J Environ Anal Chem 2003, 83 (11), 953-962.
  • Kizilkaya, H.; Dag, B.; Aral, T.; Genc, N.; Erenler, R. Journal of the Chinese Chemical Society 2020, 67 (9), 1696-1701.
  • Zamani, H. A.; Faridbod, F. Journal of Analytical Chemistry 2014, 69 (11), 1073-1078.
  • Umezawa, Y.; Bühlmann, P.; Umezawa, K.; Tohda, K.; Amemiya, S. Pure and Applied Chemistry 2000, 72 (10), 1851-2082.
  • Zamani, H. A.; Ganjali, M. R.; Behmadi, H.; Behnajady, M. A. Materials Science and Engineering: C 2009, 29 (5), 1535-1539.
  • Masrournia, M.; Zamani, H. A.; Mirrashid, H. A.; Ganjali, M. R.; Faridbod, F. Materials Science and Engineering: C 2011, 31 (3), 574-578.
  • Mizani, F.; Ganjali, M.; Faridbod, F.; Esmaeilnia, S. Int J Electrochem Sci 2013, 8, 10473-10486.
  • Ozer, T.; Isildak, I. Int J Electrochem Sci 2018, 13, 11375-11387.
  • Yari, A.; Bagheri, M.; Ghazizadeh, M. Int J Electrochem Sci 2016, 11, 6597-6608.
  • Gupta, V. K.; Jain, A.; Agarwal, S.; Maheshwari, G. Talanta 2007, 71 (5), 1964-1968.
There are 24 citations in total.

Details

Primary Language English
Subjects Food Engineering
Journal Section Research Articles
Authors

İlyas Yıldız 0000-0003-1254-1069

Ramazan Erenler 0000-0002-0505-3190

Mehmet Hakkı Alma 0000-0001-6323-7230

Ömer Işıldak 0000-0003-4690-4323

Tarık Aral 0000-0002-6612-2751

Early Pub Date January 9, 2024
Publication Date December 31, 2023
Submission Date October 11, 2023
Acceptance Date December 29, 2023
Published in Issue Year 2023 Volume: 7 Issue: 2

Cite

APA Yıldız, İ., Erenler, R., Alma, M. H., Işıldak, Ö., et al. (2023). A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions. International Journal of Chemistry and Technology, 7(2), 180-187. https://doi.org/10.32571/ijct.1374226
AMA Yıldız İ, Erenler R, Alma MH, Işıldak Ö, Aral T. A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions. Int. J. Chem. Technol. December 2023;7(2):180-187. doi:10.32571/ijct.1374226
Chicago Yıldız, İlyas, Ramazan Erenler, Mehmet Hakkı Alma, Ömer Işıldak, and Tarık Aral. “A New Potentiometric Electrode Based on Indole Derivative Molecule for the Determination of Fe (III) Ions”. International Journal of Chemistry and Technology 7, no. 2 (December 2023): 180-87. https://doi.org/10.32571/ijct.1374226.
EndNote Yıldız İ, Erenler R, Alma MH, Işıldak Ö, Aral T (December 1, 2023) A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions. International Journal of Chemistry and Technology 7 2 180–187.
IEEE İ. Yıldız, R. Erenler, M. H. Alma, Ö. Işıldak, and T. Aral, “A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions”, Int. J. Chem. Technol., vol. 7, no. 2, pp. 180–187, 2023, doi: 10.32571/ijct.1374226.
ISNAD Yıldız, İlyas et al. “A New Potentiometric Electrode Based on Indole Derivative Molecule for the Determination of Fe (III) Ions”. International Journal of Chemistry and Technology 7/2 (December 2023), 180-187. https://doi.org/10.32571/ijct.1374226.
JAMA Yıldız İ, Erenler R, Alma MH, Işıldak Ö, Aral T. A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions. Int. J. Chem. Technol. 2023;7:180–187.
MLA Yıldız, İlyas et al. “A New Potentiometric Electrode Based on Indole Derivative Molecule for the Determination of Fe (III) Ions”. International Journal of Chemistry and Technology, vol. 7, no. 2, 2023, pp. 180-7, doi:10.32571/ijct.1374226.
Vancouver Yıldız İ, Erenler R, Alma MH, Işıldak Ö, Aral T. A new potentiometric electrode based on indole derivative molecule for the determination of Fe (III) ions. Int. J. Chem. Technol. 2023;7(2):180-7.

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