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WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS

Year 2019, Volume: 8 Issue: 1, 567 - 575, 28.01.2019

Ozkan Bayram

https://doi.org/10.28948/ngumuh.517198

Abstract

   In this study, organic based polymer thin
films were obtained on various substrates using D-Limonene essential oil, which
is an organic compound by radio frequency (RF) plasma polymerization technique.
The optical band gap and absorption spectra of thin films were investigated by
Uv-VIS spectra and depending on the increased RF power, the optical band gap of the thin
films was found to be 3.19, 3.25 and 3.31 eV, respectively. WCA analyzes were
also performed to determine the wettability properties of thin films and all
thin films had hydrophilic properties and these properties were significantly
affected by increased RF power. Considering both the morphological and optical
properties of plasma polymerized (pp) D-Limonene thin films, it is thought that
these films may be an alternative to those already used in current electronic
applications due to their organic compound-based nature.

Keywords

Polymerisation organic thin films RF D-Limonene

References

  • [1] C.D. MULLER, A. FALCOU, N. RECKEFUSS, M. ROJAHN, V. WIEDERHIRN, P. RUDATI, H. FROHNE, O. NUYKEN, H. BECKER, K. MEERHOLZ, Multi-colour organic light-emitting displays by solution processing, Nature 421(6925) (2003) 829.
  • [2] Y.H. NIU, M.S. LIU, J.W. KA, J. BARDEKER, M.T. ZIN, R. SCHOFIELD, Y. CHI, A.Y. JEN, Crosslinkable Hole‐Transport Layer on Conducting Polymer for High‐Efficiency White Polymer Light‐Emitting Diodes, Adv. Mater. 19(2) (2007) 300-304.
  • [3] C.-Y. LIN, Y.-C. LIN, W.-Y. HUNG, K.-T. WONG, R.C. KWONG, S.C. XIA, Y.-H. CHEN, C.-I. WU, A thermally cured 9, 9-diarylfluorene-based triaryldiamine polymer displaying high hole mobility and remarkable ambient stability, Journal of Materials Chemistry 19(22) (2009) 3618-3623.
  • [4] C.A. ZUNIGA, S. BARLOW, S.R. MARDER, Approaches to solution-processed multilayer organic light-emitting diodes based on cross-linking, Chemistry of Materials 23(3) (2010) 658-681.
  • [5] Y. WANG, H. BENTEN, S. OHARA, D. KAWAMURA, H. OHKITA, S. ITO, Measurement of exciton diffusion in a well-defined donor/acceptor heterojunction based on a conjugated polymer and cross-linked fullerene derivative, ACS Appl. Mater. Interfaces 6(16) (2014) 14108-14115.
  • [6] S. ALANCHERRY, K. BAZAKA, M.V. JACOB, RF Plasma Polymerization of Orange Oil and Characterization of the Polymer Thin Films, Journal of Polymers and the Environment (2018) 1-9.
  • [7] M.S. WHITE, M. KALTENBRUNNER, E.D. GŁOWACKI, K. GUTNICHENKO, G. KETTLGRUBER, I. GRAZ, S. AAZOU, C. ULBRICHT, D.A. EGBE, M.C. MIRON, Ultrathin, highly flexible and stretchable PLEDs, Nature Photonics 7(10) (2013) 811.
  • [8] A. FACCHETTI, Semiconductors for organic transistors, Materials Today 10(3) (2007) 28-37.
  • [9] K. BAZAKA, M.V. JACOB, Synthesis of radio frequency plasma polymerized non-synthetic Terpinen-4-ol thin films, Materials Letters 63(18-19) (2009) 1594-1597.
  • [10] K.S. CHEN, S.J. CHANG, C.K. FENG, W.L. LIN, S.C. LIAO, Plasma Deposition and UV Light Induced Surface Grafting Polymerization of NIPAAm on Stainless Steel for Enhancing Corrosion Resistance and Its Drug Delivery Property, Polymer 10(9) (2018) 1-12.
  • [11] K. BAZAKA, M.V. JACOB, V.K. TRUONG, R.J. CRAWFORD, E.P. IVANOVA, The effect of polyterpenol thin film surfaces on bacterial viability and adhesion, Polymers 3(1) (2011) 388-404.
  • [12] C.D. EASTON, M.V. JACOB, Optical characterisation of radio frequency plasma polymerised Lavandula angustifolia essential oil thin films, Thin Solid Films 517(15) (2009) 4402-4407.
  • [13] M.V. JACOB, N.S. OLSEN, L.J. ANDERSON, K. BAZAKA, R.A. SHANKS, Plasma polymerised thin films for flexible electronic applications, Thin Solid Films 546 (2013) 167-170.
  • [14] G. LAKSHMI, A. DHILLON, D.K. AVASTHI, A.M. SIDDIQUI, M. ZULFEQUAR, Synthesis and characterization of thin films of poly(3-methyl thiophene) by rf-plasma polymerization, Materials Letters 64(15) (2010) 1672-1673.
  • [15] T. BARMAN, A.R. PAL, Pulsed DC discharge for synthesis of conjugated plasma polymerized aniline thin film, Appl. Surf. Sci. 259 (2012) 691-697.
  • [16] H. GOKTAS, Z. DEMIRCIOGLU, K. SEL, T. GUNES, I. KAYA, The optical properties of plasma polymerized polyaniline thin films, Thin Solid Films 548 (2013) 81-85.
  • [17] H.S. ABDULLA, A.I. ABBO, Optical and electrical properties of thin films of polyaniline and polypyrrole, Int J Electrochem Sci 7 (2012) 10666-10678.
  • [18] K. BAZAKA, M.V. JACOB, R.A. SHANKS, Fabrication and Characterization of RF Plasma Polymerized Thin Films from 3,7-Dimethyl-1,6-octadien-3-ol for Electronic and Biomaterial Applications, Multi-Functional Materials and Structures Iii, Pts 1 and 2, Trans Tech Publications Ltd, Stafa-Zurich, 2010, pp. 323-326.
  • [19] C.D. EASTON, M.V. JACOB, R.A. SHANKS, B.F. BOWDEN, Surface and chemical characterization of PolyLA thin films fabricated using plasma polymerization, Chemical Vapor Deposition 15(7‐9) (2009) 179-185.
  • [20] A. AL-JUMAILI, K. BAZAKA, M.V. JACOB, Retention of Antibacterial Activity in Geranium Plasma Polymer Thin Films, Nanomaterials 7(9) (2017) 23.
  • [21] M. CLAUDINO, M. JONSSON, M. JOHANSSON, Utilizing thiol–ene coupling kinetics in the design of renewable thermoset resins based on D-Limonene and polyfunctional thiols, RSC Adv. 4(20) (2014) 10317-10329.
  • [22] O. BAYRAM, O. SIMSEK, Investigation of the effect of RF energy on optical, morphological, chemical and antibacterial properties of PolyTerpenol thin films obtained by RF-PECVD technique, Journal of Materials Science: Materials in Electronics (2018) 1-8.
  • [23] J. TAUC, A. MENTH, D. WOOD, Optical and magnetic investigations of the localized states in semiconducting glasses, Physical Review Letters 25(11) (1970) 749.
  • [24] C. EASTON, M. JACOB, Optical characterisation of radio frequency plasma polymerised Lavandula angustifolia essential oil thin films, Thin Solid Films 517(15) (2009) 4402-4407.
  • [25] A. KUMAR, D.S. GRANT, K. BAZAKA, M.V. JACOB, Tailoring terpenoid plasma polymer properties by controlling the substrate temperature during PECVD, J. Appl. Polym. Sci. 135(5) (2018).
  • [26] D. BHATTACHARYYA, H. XU, R.R. DESHMUKH, R.B. TIMMONS, K.T. NGUYEN, Surface chemistry and polymer film thickness effects on endothelial cell adhesion and proliferation, Journal of Biomedical Materials Research Part A 94A(2) (2010) 640-648.

PLAZMA POLİMERİZE D-LİMONENE İNCE FİLMLERİN ISLANABİLİRLİK, OPTİK VE KİMYASAL ÖZELLİKLERİ

Year 2019, Volume: 8 Issue: 1, 567 - 575, 28.01.2019

Ozkan Bayram

https://doi.org/10.28948/ngumuh.517198

Abstract

   Bu çalışmada, radyo frekansı (RF) plazma
polimerizasyon tekniği ile organik bir bileşik olan D-Limonene esansiyel yağı
kullanılarak çeşitli alt tabakalar üzerinde organik bazlı polimer ince filmler
elde edilmiştir. İnce filmlerin optik bant aralığı ve absorpsiyon spektrumları Uv-VIS
spektroskopisi kullanılarak incelenmiş ve artan RF gücüne bağlı olarak, optik
bant aralığı sırasıyla 3,19, 3,25 ve 3,31 eV olarak belirlenmiştir. İnce
filmlerin ıslanabilirlik özelliklerini belirlemek için WCA analizleri de
gerçekleştirilmiş ve tüm ince filmlerin hidrofilik özelliklere sahip olduğu ve bu
özelliklerin artan RF gücünden önemli ölçüde etkilendiği belirlenmiştir. Plazma
ile polimerleştirilmiş D-Limonene ince filmlerin, hem morfolojik hem de optik
özellikleri göz önünde bulundurulduğunda, bu filmlerin organik bileşik tabanlı
olmaları nedeniyle, mevcut elektronik uygulamalarda kullanılanlara alternatif
olabileceği düşünülmektedir.

Keywords

Polimerizasyon organik ince filmler RF D-Limonene

References

  • [1] C.D. MULLER, A. FALCOU, N. RECKEFUSS, M. ROJAHN, V. WIEDERHIRN, P. RUDATI, H. FROHNE, O. NUYKEN, H. BECKER, K. MEERHOLZ, Multi-colour organic light-emitting displays by solution processing, Nature 421(6925) (2003) 829.
  • [2] Y.H. NIU, M.S. LIU, J.W. KA, J. BARDEKER, M.T. ZIN, R. SCHOFIELD, Y. CHI, A.Y. JEN, Crosslinkable Hole‐Transport Layer on Conducting Polymer for High‐Efficiency White Polymer Light‐Emitting Diodes, Adv. Mater. 19(2) (2007) 300-304.
  • [3] C.-Y. LIN, Y.-C. LIN, W.-Y. HUNG, K.-T. WONG, R.C. KWONG, S.C. XIA, Y.-H. CHEN, C.-I. WU, A thermally cured 9, 9-diarylfluorene-based triaryldiamine polymer displaying high hole mobility and remarkable ambient stability, Journal of Materials Chemistry 19(22) (2009) 3618-3623.
  • [4] C.A. ZUNIGA, S. BARLOW, S.R. MARDER, Approaches to solution-processed multilayer organic light-emitting diodes based on cross-linking, Chemistry of Materials 23(3) (2010) 658-681.
  • [5] Y. WANG, H. BENTEN, S. OHARA, D. KAWAMURA, H. OHKITA, S. ITO, Measurement of exciton diffusion in a well-defined donor/acceptor heterojunction based on a conjugated polymer and cross-linked fullerene derivative, ACS Appl. Mater. Interfaces 6(16) (2014) 14108-14115.
  • [6] S. ALANCHERRY, K. BAZAKA, M.V. JACOB, RF Plasma Polymerization of Orange Oil and Characterization of the Polymer Thin Films, Journal of Polymers and the Environment (2018) 1-9.
  • [7] M.S. WHITE, M. KALTENBRUNNER, E.D. GŁOWACKI, K. GUTNICHENKO, G. KETTLGRUBER, I. GRAZ, S. AAZOU, C. ULBRICHT, D.A. EGBE, M.C. MIRON, Ultrathin, highly flexible and stretchable PLEDs, Nature Photonics 7(10) (2013) 811.
  • [8] A. FACCHETTI, Semiconductors for organic transistors, Materials Today 10(3) (2007) 28-37.
  • [9] K. BAZAKA, M.V. JACOB, Synthesis of radio frequency plasma polymerized non-synthetic Terpinen-4-ol thin films, Materials Letters 63(18-19) (2009) 1594-1597.
  • [10] K.S. CHEN, S.J. CHANG, C.K. FENG, W.L. LIN, S.C. LIAO, Plasma Deposition and UV Light Induced Surface Grafting Polymerization of NIPAAm on Stainless Steel for Enhancing Corrosion Resistance and Its Drug Delivery Property, Polymer 10(9) (2018) 1-12.
  • [11] K. BAZAKA, M.V. JACOB, V.K. TRUONG, R.J. CRAWFORD, E.P. IVANOVA, The effect of polyterpenol thin film surfaces on bacterial viability and adhesion, Polymers 3(1) (2011) 388-404.
  • [12] C.D. EASTON, M.V. JACOB, Optical characterisation of radio frequency plasma polymerised Lavandula angustifolia essential oil thin films, Thin Solid Films 517(15) (2009) 4402-4407.
  • [13] M.V. JACOB, N.S. OLSEN, L.J. ANDERSON, K. BAZAKA, R.A. SHANKS, Plasma polymerised thin films for flexible electronic applications, Thin Solid Films 546 (2013) 167-170.
  • [14] G. LAKSHMI, A. DHILLON, D.K. AVASTHI, A.M. SIDDIQUI, M. ZULFEQUAR, Synthesis and characterization of thin films of poly(3-methyl thiophene) by rf-plasma polymerization, Materials Letters 64(15) (2010) 1672-1673.
  • [15] T. BARMAN, A.R. PAL, Pulsed DC discharge for synthesis of conjugated plasma polymerized aniline thin film, Appl. Surf. Sci. 259 (2012) 691-697.
  • [16] H. GOKTAS, Z. DEMIRCIOGLU, K. SEL, T. GUNES, I. KAYA, The optical properties of plasma polymerized polyaniline thin films, Thin Solid Films 548 (2013) 81-85.
  • [17] H.S. ABDULLA, A.I. ABBO, Optical and electrical properties of thin films of polyaniline and polypyrrole, Int J Electrochem Sci 7 (2012) 10666-10678.
  • [18] K. BAZAKA, M.V. JACOB, R.A. SHANKS, Fabrication and Characterization of RF Plasma Polymerized Thin Films from 3,7-Dimethyl-1,6-octadien-3-ol for Electronic and Biomaterial Applications, Multi-Functional Materials and Structures Iii, Pts 1 and 2, Trans Tech Publications Ltd, Stafa-Zurich, 2010, pp. 323-326.
  • [19] C.D. EASTON, M.V. JACOB, R.A. SHANKS, B.F. BOWDEN, Surface and chemical characterization of PolyLA thin films fabricated using plasma polymerization, Chemical Vapor Deposition 15(7‐9) (2009) 179-185.
  • [20] A. AL-JUMAILI, K. BAZAKA, M.V. JACOB, Retention of Antibacterial Activity in Geranium Plasma Polymer Thin Films, Nanomaterials 7(9) (2017) 23.
  • [21] M. CLAUDINO, M. JONSSON, M. JOHANSSON, Utilizing thiol–ene coupling kinetics in the design of renewable thermoset resins based on D-Limonene and polyfunctional thiols, RSC Adv. 4(20) (2014) 10317-10329.
  • [22] O. BAYRAM, O. SIMSEK, Investigation of the effect of RF energy on optical, morphological, chemical and antibacterial properties of PolyTerpenol thin films obtained by RF-PECVD technique, Journal of Materials Science: Materials in Electronics (2018) 1-8.
  • [23] J. TAUC, A. MENTH, D. WOOD, Optical and magnetic investigations of the localized states in semiconducting glasses, Physical Review Letters 25(11) (1970) 749.
  • [24] C. EASTON, M. JACOB, Optical characterisation of radio frequency plasma polymerised Lavandula angustifolia essential oil thin films, Thin Solid Films 517(15) (2009) 4402-4407.
  • [25] A. KUMAR, D.S. GRANT, K. BAZAKA, M.V. JACOB, Tailoring terpenoid plasma polymer properties by controlling the substrate temperature during PECVD, J. Appl. Polym. Sci. 135(5) (2018).
  • [26] D. BHATTACHARYYA, H. XU, R.R. DESHMUKH, R.B. TIMMONS, K.T. NGUYEN, Surface chemistry and polymer film thickness effects on endothelial cell adhesion and proliferation, Journal of Biomedical Materials Research Part A 94A(2) (2010) 640-648.
There are 26 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Materials and Metallurgical Engineering
Authors

Ozkan Bayram 0000-0002-0741-3129

Publication Date January 28, 2019
Submission Date September 18, 2018
Acceptance Date November 19, 2018
Published in Issue Year 2019 Volume: 8 Issue: 1

Cite

APA Bayram, O. (2019). WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 8(1), 567-575. https://doi.org/10.28948/ngumuh.517198
AMA Bayram O. WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS. NOHU J. Eng. Sci. January 2019;8(1):567-575. doi:10.28948/ngumuh.517198
Chicago Bayram, Ozkan. “WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8, no. 1 (January 2019): 567-75. https://doi.org/10.28948/ngumuh.517198.
EndNote Bayram O (January 1, 2019) WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8 1 567–575.
IEEE O. Bayram, “WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS”, NOHU J. Eng. Sci., vol. 8, no. 1, pp. 567–575, 2019, doi: 10.28948/ngumuh.517198.
ISNAD Bayram, Ozkan. “WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8/1 (January 2019), 567-575. https://doi.org/10.28948/ngumuh.517198.
JAMA Bayram O. WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS. NOHU J. Eng. Sci. 2019;8:567–575.
MLA Bayram, Ozkan. “WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 8, no. 1, 2019, pp. 567-75, doi:10.28948/ngumuh.517198.
Vancouver Bayram O. WETTABILITY, OPTICAL AND CHEMICAL CHARACTERISTICS OF PLASMA-POLYMERIZED D-LIMONENE THIN FILMS. NOHU J. Eng. Sci. 2019;8(1):567-75.
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