Pinus brutia Ten. (Kızılçam) Kozalak ve Yaprak Biyomasının Boya Biyosorpsiyon/Desorpsiyon Potansiyeli
Öz
Özet: Biyosorbent rejenerasyonu ve tekrar kullanımı, biyosorpsiyon prosesini daha ekonomik hale getirmek için oldukça önemlidir. Desorpsiyon çalışmaları, biyosorpsiyon olayının mekanizmasının ortaya konulması, biyosorbentin geri kazanımı ve tekrar biyosorpsiyon prosesinde kullanımı için yapılmaktadır. Başarılı bir desorpsiyon işlemi, biyosorbentin çeşidine ve biyosorpsiyon mekanizmasına göre değişen uygun bir desorbent seçimini gerektirmektedir. Seçilen desorbentler etkili, ucuz ve zararsız olmalıdır. Bu çalışmada, kızılçam kozalak ve yaprak biyosorbentleri tarafından biyosorplanan Basic Red 46 ve Acid Yellow 220 boyalarının biyosorbent yüzeylerinden desorpsiyonu için seyreltik (0,1 M) HCl ve NaOH çözeltileri kullanılmıştır. Biyosorbentlerin boya biyosorpsiyonunda yeniden kullanım potansiyellerini değerlendirmek için ardışık biyosorpsiyon/desorpsiyon döngüsü aynı biyosorbentle üç kez tekrarlanmıştır. 0,1 M HCl kullanımı ile Basic Red 46 boyasının kozalak ve yaprak biyosorbentlerinden en düşük boya desorpsiyonu sırası ile %90,88 ve %95,99 olarak belirlenmiştir. 0,1 M NaOH kullanımı ile Acid Yellow 220 boyası için kozalak ve yaprak biyosorbentlerinden en düşük boya desorpsiyonu sırası ile %88,37 ve %86,79 olarak bulunmuştur. Sonuçlar, bu biyosorbentlerin ekonomik bir şekilde boya biyosorpsiyon çalışmalarında tekrar tekrar kullanılabileceğini göstermiştir.
Anahtar Kelimeler: Kızılçam, Boya, Biyosorpsiyon, Desorpsiyon
Dye Biosorption/Desorption Potential of Pinus brutia Ten. (Red pine)
Cone and Leaf Biomass
Abstract: The regeneration and reuse of biosorbent is quite important in order to make the biosorption process more economical. Desorption studies were performed for elucidating the mechanism of biosorption case, recovery of biosorbent and reuse of biosorbent at biosorption process. Selection of an appropriate eluent is crucial for successful regeneration. A successful desorption process requires the selection of a proper desorbent, which depends on the type of biosorbent and the mechanism of biosorption. The selected desorbents should be effective, cheap and harmless. In this study, dilute (0.1 M) HCl and NaOH solutions were employed for desorption of Basic Red 46 and Acid Yellow 220 dyes biosorbed by the cone and leaf biosorbents of red pine from the biosorbent surfaces. In order to evaluate the reuse potential of biosorbents at the dye biosorption, consecutive biosorption/desorption cycles were repeated three times with the same biosorbent. The minimum dye desorption from the cone and leaf biosorbents for Basic Red 46 by using 0.1 M HCl was defined as %90.88 and %95.99, respectively. For Acid Yellow 220, the minimum dye desorption from the cone and leaf biosorbents by employing 0.1 M NaOH was found as %88.37 and %86.79, respectively. The results displayed that these biosorbents as economically could be repeatedly used in the dye biosorption studies.
Key words: Red pine, Dye, Biosorption, Desorption
Anahtar Kelimeler
Kaynakça
- Aksu, Z., 2005. Application of biosorption for the removal of organic pollutants: a review. Process Biochem. 40:997-1026.
- Aravindhan, R., Rao, J.R., Nair, B.U., 2007. Removal of basic yellow dye from aqueous solution by sorption on green alga Caulerpa scalpelliformis. J. Hazard. Mater. 142:68-76.
- Barka, N., Abdennouri, M., El Makhfouk, M., 2011. Removal of Methylene Blue and Eriochrome Black T from aqueous solutions by biosorption on Scolymus hispanicus thermodynamics. J. Taiwan Inst. Chem. E. 42:320-326. equilibrium and
- Bayramoğlu, G., Çelik, G., Arıca, M.Y., 2006. Studies on accumulation of uranium by fungus sajorcaju. J. Hazard. Mater. 136:343-351. Lentinus
- Bello, O.S., Adelaide, O.M., Hammed, M.A., Popoola, O.A.M., 2010. Kinetic and equilibrium studies of methylene blue removal from aqueous solution by adsorption on treated sawdust. Macedonian J. Chem. Eng. 29:77-85.
- Blázquez, G., Martín-Lara, M.A., Dionisio-Ruiz, E., Tenorio, G., Calero, M., 2012. Copper biosorption by pine cone shell and thermal decomposition study of the exhausted biosorbent. J. Ind. Eng. Chem. 18:1741-1750.
- Bozanta, E., Ökmen G., 2011. Biyosorpsiyon ve mikroorganizmalar. Türk Bil. Der. Derg. 4:69-77.
- Cheng, W., Wang, S.G., Lu, L., Gong, W.X., Liu, X.W., Gao, B.Y., Zhang, H.Y., 2008. Removal of malachite green (MG) from aqueous solutions by native and heat-treated anaerobic granular sludge. Biochem. Eng. J. 39:538-546.
- Couto, S.R., 2009. Dye removal by immobilised fungi. Biotechnol. Adv. 27:227-235.
- Dawood, S., Sen, T.K., 2012. Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res. 46:1933-1946.
- Ertaş, M., Acemioğlu, B., Alma, M.H., Usta, M., 2010. Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust. J. Hazard. Mater. 183:421-427.
- Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L., 2010. Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes. Bioresour. Technol. 101:9500-9507.
- Ferrero, F., 2007. Dye removal by low cost adsorbents: hazelnut shells in comparison with wood sawdust. J. Hazard. Mater. 142:144-152.
- Gündoğdu, A., Özdeş, D., Duran, C., Bulut, V.N., Soylak, M., Şentürk, H.B., 2009. Biosorption of Pb(II) ions from aqueous solution by pine bark (Pinus brutia Ten.). Chem. Eng. J. 153:62-69.
- Gupta, V.K., Suhas, 2009. Application of low-cost adsorbents for dye removal - A review. J. Environ. Manage. 90:2313-2342.
- Hai, F.I., Yamamoto, K., Fukushi, K., 2007. Hybrid treatment systems for dye wastewater. Crit. Rev. Env. Sci. Technol. 37:315-377.
- Hameed, B.H., 2009. Grass waste: A novel sorbent for the removal of basic dye from aqueous solution. J. Hazard. Mater. 166:233-238.
- Hamutoğlu, R., Dinçsoy, A.B., Cansaran-Duman, D., Aras, S., 2012. Biyosorpsiyon, adsorpsiyon ve fitoremediasyon yöntemleri ve uygulamaları. Türk Hij. Den. Biyol. Derg. 69:235-53.
- Han, R., Ding, D., Xu, Y., Zou, W., Wang, Y., Li, Y., Zou, L., 2008. Use of rice husk for the adsorption of congo red from aqueous solution in column mode. Bioresour. Technol. 99:2938-2946.
- Husain, Q., 2006. Potential applications of the oxidoreductive enzymes in the decolorization and detoxification of textile and other synthetic dyes from polluted water: a review. Crit. Rev. Biotechnol. 26:201-221.
- İçgen, Y., Kaya, Z., Çengel, B., Velioğlu, E., Öztürk, H., Önde, S., 2006. Potential impact of forest management and tree improvement on genetic diversity of Turkish red pine (Pinus brutia Ten.) plantations in Turkey. Forest Ecol. Manage. 225:328-336.
- Karagöz, G., Demirci, M., 2012. Forestry property of Turkey, General Directorate of Forestry, No: 85, Ankara.
- Lima, E.C., Royer, B., Vaghetti, J.C.P., Simon, N.M., DA Cunha, B.M., Pavan, F.A., Benvenutti, E.V., Veses, R.C., Airoldi, C., 2008. Application of Brazilian-pine fruit coat as a biosorbent to removal of reactive red 194 textile dye from aqueous solution, Kinetics and equilibrium study. J. Hazard. Mater. 155:536-550.
- Liu, R., Zhang, B., Mei, D., Zhang, H., Liu, J., 2011. Adsorption of methyl violet from aqueous solution by halloysite nanotubes. Desalination 268:111-116.
- Mahmoodi, N.M., Hayati, B., Arami, M., Lan, C., 2011. Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination 268:117-125.
- Mittal, A., Mittal, J., Malviya, A., Gupta, V.K., 2010. Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials. J. Colloid Interface Sci. 344:497-507.
- Ofomaja, A.E., Naidoo, E.B., 2011. Biosorption of copper from aqueous solution by chemically activated pine cone: A kinetic study. Chem. Eng. J. 175:260-270.
- Ofomaja, A.E., Naidoo, E.B., Modise, S.J., 2009. Removal of copper (II) from aqueous solution by pine and base modified pine cone powder as biosorbent J. Hazard. Mater. 168:909-917.
- Ofomaja, A.E., Pholosi, A., Naidoo, E.B., 2013. Kinetics and competitive modeling of cesium biosortion onto chemically modified pine cone powder. J. Taiwan Ins. Chem. Eng. 44:943-951.
- Rauf, M.A., Qadri, S.M., Ashraf, S., Al-Mansoori, K.M., 2009. Adsorption studies of Toluidine Blue from aqueous solutions onto gypsum. Chem. Eng. J. 150:90-95.
- Sen, T.K., Afroze, S., Ang, H.M., 2011. Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata. Water Air Soil Pollut. 218:499-515.
- Vijayaraghavan, K., Yun, Y.S., 2008b. Biosorption of C.I. Reactive Black 5 from aqueous solution using acid-treated biomass of brown seaweed Laminaria sp.. Dyes Pigments 76:726-732.
Yıl 2014,
Cilt: 17 Sayı: 3, 19 - 25, 11.02.2015
Öz
Biyosorbent rejenerasyonu ve tekrar kullanımı, biyosorpsiyon prosesini daha ekonomik hale getirmek içinoldukça önemlidir.biyosorbentin geri kazanımı ve tekrar biyosorpsiyon prosesinde kullanımı için yapılmaktadır. Başarılı birbiyosorpsiyon
Anahtar Kelimeler
Kaynakça
- Aksu, Z., 2005. Application of biosorption for the removal of organic pollutants: a review. Process Biochem. 40:997-1026.
- Aravindhan, R., Rao, J.R., Nair, B.U., 2007. Removal of basic yellow dye from aqueous solution by sorption on green alga Caulerpa scalpelliformis. J. Hazard. Mater. 142:68-76.
- Barka, N., Abdennouri, M., El Makhfouk, M., 2011. Removal of Methylene Blue and Eriochrome Black T from aqueous solutions by biosorption on Scolymus hispanicus thermodynamics. J. Taiwan Inst. Chem. E. 42:320-326. equilibrium and
- Bayramoğlu, G., Çelik, G., Arıca, M.Y., 2006. Studies on accumulation of uranium by fungus sajorcaju. J. Hazard. Mater. 136:343-351. Lentinus
- Bello, O.S., Adelaide, O.M., Hammed, M.A., Popoola, O.A.M., 2010. Kinetic and equilibrium studies of methylene blue removal from aqueous solution by adsorption on treated sawdust. Macedonian J. Chem. Eng. 29:77-85.
- Blázquez, G., Martín-Lara, M.A., Dionisio-Ruiz, E., Tenorio, G., Calero, M., 2012. Copper biosorption by pine cone shell and thermal decomposition study of the exhausted biosorbent. J. Ind. Eng. Chem. 18:1741-1750.
- Bozanta, E., Ökmen G., 2011. Biyosorpsiyon ve mikroorganizmalar. Türk Bil. Der. Derg. 4:69-77.
- Cheng, W., Wang, S.G., Lu, L., Gong, W.X., Liu, X.W., Gao, B.Y., Zhang, H.Y., 2008. Removal of malachite green (MG) from aqueous solutions by native and heat-treated anaerobic granular sludge. Biochem. Eng. J. 39:538-546.
- Couto, S.R., 2009. Dye removal by immobilised fungi. Biotechnol. Adv. 27:227-235.
- Dawood, S., Sen, T.K., 2012. Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res. 46:1933-1946.
- Ertaş, M., Acemioğlu, B., Alma, M.H., Usta, M., 2010. Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust. J. Hazard. Mater. 183:421-427.
- Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L., 2010. Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes. Bioresour. Technol. 101:9500-9507.
- Ferrero, F., 2007. Dye removal by low cost adsorbents: hazelnut shells in comparison with wood sawdust. J. Hazard. Mater. 142:144-152.
- Gündoğdu, A., Özdeş, D., Duran, C., Bulut, V.N., Soylak, M., Şentürk, H.B., 2009. Biosorption of Pb(II) ions from aqueous solution by pine bark (Pinus brutia Ten.). Chem. Eng. J. 153:62-69.
- Gupta, V.K., Suhas, 2009. Application of low-cost adsorbents for dye removal - A review. J. Environ. Manage. 90:2313-2342.
- Hai, F.I., Yamamoto, K., Fukushi, K., 2007. Hybrid treatment systems for dye wastewater. Crit. Rev. Env. Sci. Technol. 37:315-377.
- Hameed, B.H., 2009. Grass waste: A novel sorbent for the removal of basic dye from aqueous solution. J. Hazard. Mater. 166:233-238.
- Hamutoğlu, R., Dinçsoy, A.B., Cansaran-Duman, D., Aras, S., 2012. Biyosorpsiyon, adsorpsiyon ve fitoremediasyon yöntemleri ve uygulamaları. Türk Hij. Den. Biyol. Derg. 69:235-53.
- Han, R., Ding, D., Xu, Y., Zou, W., Wang, Y., Li, Y., Zou, L., 2008. Use of rice husk for the adsorption of congo red from aqueous solution in column mode. Bioresour. Technol. 99:2938-2946.
- Husain, Q., 2006. Potential applications of the oxidoreductive enzymes in the decolorization and detoxification of textile and other synthetic dyes from polluted water: a review. Crit. Rev. Biotechnol. 26:201-221.
- İçgen, Y., Kaya, Z., Çengel, B., Velioğlu, E., Öztürk, H., Önde, S., 2006. Potential impact of forest management and tree improvement on genetic diversity of Turkish red pine (Pinus brutia Ten.) plantations in Turkey. Forest Ecol. Manage. 225:328-336.
- Karagöz, G., Demirci, M., 2012. Forestry property of Turkey, General Directorate of Forestry, No: 85, Ankara.
- Lima, E.C., Royer, B., Vaghetti, J.C.P., Simon, N.M., DA Cunha, B.M., Pavan, F.A., Benvenutti, E.V., Veses, R.C., Airoldi, C., 2008. Application of Brazilian-pine fruit coat as a biosorbent to removal of reactive red 194 textile dye from aqueous solution, Kinetics and equilibrium study. J. Hazard. Mater. 155:536-550.
- Liu, R., Zhang, B., Mei, D., Zhang, H., Liu, J., 2011. Adsorption of methyl violet from aqueous solution by halloysite nanotubes. Desalination 268:111-116.
- Mahmoodi, N.M., Hayati, B., Arami, M., Lan, C., 2011. Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination 268:117-125.
- Mittal, A., Mittal, J., Malviya, A., Gupta, V.K., 2010. Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials. J. Colloid Interface Sci. 344:497-507.
- Ofomaja, A.E., Naidoo, E.B., 2011. Biosorption of copper from aqueous solution by chemically activated pine cone: A kinetic study. Chem. Eng. J. 175:260-270.
- Ofomaja, A.E., Naidoo, E.B., Modise, S.J., 2009. Removal of copper (II) from aqueous solution by pine and base modified pine cone powder as biosorbent J. Hazard. Mater. 168:909-917.
- Ofomaja, A.E., Pholosi, A., Naidoo, E.B., 2013. Kinetics and competitive modeling of cesium biosortion onto chemically modified pine cone powder. J. Taiwan Ins. Chem. Eng. 44:943-951.
- Rauf, M.A., Qadri, S.M., Ashraf, S., Al-Mansoori, K.M., 2009. Adsorption studies of Toluidine Blue from aqueous solutions onto gypsum. Chem. Eng. J. 150:90-95.
- Sen, T.K., Afroze, S., Ang, H.M., 2011. Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata. Water Air Soil Pollut. 218:499-515.
- Vijayaraghavan, K., Yun, Y.S., 2008b. Biosorption of C.I. Reactive Black 5 from aqueous solution using acid-treated biomass of brown seaweed Laminaria sp.. Dyes Pigments 76:726-732.
Toplam 32 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Bölüm | EKOLOJİ (Ecology) |
| Yazarlar | |
| Yayımlanma Tarihi | 11 Şubat 2015 |
| Yayımlandığı Sayı | Yıl 2014 Cilt: 17 Sayı: 3 |