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Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi

Yıl 2022, Cilt: 24 Sayı: 70, 81 - 90, 17.01.2022
https://doi.org/10.21205/deufmd.2022247009

Öz

Son yıllarda, geçiş metali kalkojenleri (GMK) kendilerine özgü fiziksel ve kimyasal özelliklerinden dolayı çokça çalışılan malzeme gruplarından biri olmuştur. GMK’ler, optoelektronik uygulamalarda, hidrojen evrim reaksiyonları, enerji depolama sistemleri, güneş pili uygulamalarında ve radar emici sistemlerde sıkça kullanılmaktadır. Bu çalışmada, farklı çözücüler ve ısıl işlem süreçleri kullanılarak üretilen GMK grubundan olan MoS2 ince filmlerinin yapısal özellikleri araştırılmıştır. İnce filmler sol-gel spin kaplama yöntemi ile üretilmiştir. Filmlerin kristalizasyonu farklı sıcaklık değerlerinde vakum altında tutulan ve azot gazı (N2) akışı sağlanan fırın sisteminde sağlanmıştır. Isıl işlem sıcaklığı ve çözücü kimyasalın etkisi yapısal analiz metotları ile değerlendirilmiştir. Bu kapsamda, X-ışını kırınım metodu (XRD) ve Raman saçınım ve taramalı elektron mikroskop (SEM) metodu filmlerin yapısal analizlerinin yapılmasında kullanılmıştır.

Kaynakça

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  • Xu, X., W. Zhong, X. Zhang, J. Dou, Z. Xiong, Y. Sun, T. Wang, and Y. Du. 2019. Flexible symmetric supercapacitor with ultrahigh energy density based on NiS/MoS2@N-rGO hybrids electrode, J Colloid Interface Sci, 543: p, 147-155, DOI: 10.1016/j.jcis.2019.02.054.
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  • Han, J.K., S. Kim, S. Jang, Y.R. Lim, S.-W. Kim, H. Chang, W. Song, S.S. Lee, J. Lim, K.-S. An, and S. Myung. 2019. Tunable piezoelectric nanogenerators using flexoelectricity of well-ordered hollow 2D MoS2 shells arrays for energy harvesting, Nano Energy, 61: p, 471-477, DOI: 10.1016/j.nanoen.2019.05.017.
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Investigation of the Effect of Solvent and Heat Treatment Process on Structural Properties of MoS2 Thin Films

Yıl 2022, Cilt: 24 Sayı: 70, 81 - 90, 17.01.2022
https://doi.org/10.21205/deufmd.2022247009

Öz

In recent years, transition metal dichalcogenides (TMDCs) have become one of the most studied material groups due to their unique physical and chemical properties. The TMDCs are frequently used in optoelectronic applications, hydrogen evolution reactions, energy storage systems, solar cells, and radar absorbing systems. In this study, the structural properties of MoS2 thin films, belonging to one of the TMDCs group, produced by using different solvents and heat treatment processes were investigated. Thin films were produced by using the sol-gel spin coating technique. The crystallization of the films was ensured at different heat treatment temperature values under a vacuum atmosphere by introducing N2 gas flow. The effects of the heat treatment temperature and chemical solvent were evaluated by the structural characterizations techniques. Within this scope, the X-ray diffraction method (XRD), Raman scattering, and scanning electron microscope (SEM) were used to investigate the structural properties of films.

Kaynakça

  • Lim, Y.R., W. Song, J.K. Han, Y.B. Lee, S.J. Kim, S. Myung, S.S. Lee, K.S. An, C.J. Choi, and J. Lim. 2016. Wafer-Scale, Homogeneous MoS2 Layers on Plastic Substrates for Flexible Visible-Light Photodetectors, Adv Mater, 28(25): p, 5025-30, DOI: 10.1002/adma.201600606.
  • Zardkhoshoui, A.M. and S.S.H. Davarani. 2018. Flexible asymmetric supercapacitors based on CuO@MnO2-rGO and MoS2-rGO with ultrahigh energy density, Journal of Electroanalytical Chemistry, 827: p, 221-229, DOI: 10.1016/j.jelechem.2018.08.023.
  • Sun, B., T. Shi, Z. Liu, Y. Wu, J. Zhou, and G. Liao. 2018. Large-area flexible photodetector based on atomically thin MoS2/graphene film, Materials & Design, 154: p, 1-7, DOI: 10.1016/j.matdes.2018.05.017.
  • Xu, X., W. Zhong, X. Zhang, J. Dou, Z. Xiong, Y. Sun, T. Wang, and Y. Du. 2019. Flexible symmetric supercapacitor with ultrahigh energy density based on NiS/MoS2@N-rGO hybrids electrode, J Colloid Interface Sci, 543: p, 147-155, DOI: 10.1016/j.jcis.2019.02.054.
  • Carroll, G.M., H. Zhang, J.R. Dunklin, E.M. Miller, N.R. Neale, and J. van de Lagemaat. 2019. Unique interfacial thermodynamics of few-layer 2D MoS2 for (photo)electrochemical catalysis, Energy & Environmental Science, 12(5): p, 1648-1656, DOI: 10.1039/c9ee00513g.
  • Han, J.K., S. Kim, S. Jang, Y.R. Lim, S.-W. Kim, H. Chang, W. Song, S.S. Lee, J. Lim, K.-S. An, and S. Myung. 2019. Tunable piezoelectric nanogenerators using flexoelectricity of well-ordered hollow 2D MoS2 shells arrays for energy harvesting, Nano Energy, 61: p, 471-477, DOI: 10.1016/j.nanoen.2019.05.017.
  • Huo, N., J. Yang, L. Huang, Z. Wei, S.S. Li, S.H. Wei, and J. Li. 2015. Tunable Polarity Behavior and Self-Driven Photoswitching in p-WSe(2)/n-WS(2) Heterojunctions, Small, 11(40): p, 5430-8, DOI: 10.1002/smll.201501206.
  • Yazyev, O.V. and A. Kis. 2015. MoS 2 and semiconductors in the flatland, Materials Today, 18(1): p, 20-30, DOI: 10.1016/j.mattod.2014.07.005.
  • Furchi, M.M., A. Pospischil, F. Libisch, J. Burgdorfer, and T. Mueller. 2014. Photovoltaic effect in an electrically tunable van der Waals heterojunction, Nano Lett, 14(8): p, 4785-91, DOI: 10.1021/nl501962c.
  • Choi, W., N. Choudhary, G.H. Han, J. Park, D. Akinwande, and Y.H. Lee. 2017. Recent development of two-dimensional transition metal dichalcogenides and their applications, Materials Today, 20(3): p, 116-130, DOI: 10.1016/j.mattod.2016.10.002.
  • Gołasa, K., M. Grzeszczyk, K.P. Korona, R. Bożek, J. Binder, J. Szczytko, A. Wysmołek, and A. Babiński. 2013. Optical Properties of Molybdenum Disulfide (MoS_2), Acta Physica Polonica A, 124(5): p, 849-851, DOI: 10.12693/APhysPolA.124.849.
  • Lin, Y.C., W. Zhang, J.K. Huang, K.K. Liu, Y.H. Lee, C.T. Liang, C.W. Chu, and L.J. Li. 2012. Wafer-scale MoS2 thin layers prepared by MoO3 sulfurization, Nanoscale, 4(20): p, 6637-41, DOI: 10.1039/c2nr31833d.
  • Ben Amara, I., E. Ben Salem, and S. Jaziri. 2016. Optoelectronic response and excitonic properties of monolayer MoS2, Journal of Applied Physics, 120(5): p, 051707, DOI: 10.1063/1.4958948.
  • Friedman, A.L., A.T. Hanbicki, F.K. Perkins, G.G. Jernigan, J.C. Culbertson, and P.M. Campbell. 2017. Evidence for Chemical Vapor Induced 2H to 1T Phase Transition in MoX2 (X = Se, S) Transition Metal Dichalcogenide Films, Sci Rep, 7(1): p, 3836, DOI: 10.1038/s41598-017-04224-4.
  • Calandra, M. 2013. Chemically exfoliated single-layerMoS2: Stability, lattice dynamics, and catalytic adsorption from first principles, Physical Review B, 88(24), DOI: 10.1103/PhysRevB.88.245428.
  • Eda, G., H. Yamaguchi, D. Voiry, T. Fujita, M. Chen, and M. Chhowalla. 2011. Photoluminescence from chemically exfoliated MoS2, Nano Lett, 11(12): p, 5111-6, DOI: 10.1021/nl201874w.
  • George, A.S., Z. Mutlu, R. Ionescu, R.J. Wu, J.S. Jeong, H.H. Bay, Y. Chai, K.A. Mkhoyan, M. Ozkan, and C.S. Ozkan. 2014. Wafer Scale Synthesis and High Resolution Structural Characterization of Atomically Thin MoS2Layers, Advanced Functional Materials, 24(47): p, 7461-7466, DOI: 10.1002/adfm.201402519.
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  • He, M., Y.-J. Lin, C.-M. Chiu, W. Yang, B. Zhang, D. Yun, Y. Xie, and Z.-H. Lin. 2018. A flexible photo-thermoelectric nanogenerator based on MoS2/PU photothermal layer for infrared light harvesting, Nano Energy, 49: p, 588-595, DOI: 10.1016/j.nanoen.2018.04.072.
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  • Cheng, R., D. Li, H. Zhou, C. Wang, A. Yin, S. Jiang, Y. Liu, Y. Chen, Y. Huang, and X. Duan. 2014. Electroluminescence and photocurrent generation from atomically sharp WSe2/MoS2 heterojunction p-n diodes, Nano Lett, 14(10): p, 5590-7, DOI: 10.1021/nl502075n.
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  • Wang, H., F. Liu, W. Fu, Z. Fang, W. Zhou, and Z. Liu. 2014. Two-dimensional heterostructures: fabrication, characterization, and application, Nanoscale, 6(21): p, 12250-72, DOI: 10.1039/c4nr03435j.
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  • Huo, N., Y. Yang, and J. Li. 2017. Optoelectronics based on 2D TMDs and heterostructures, Journal of Semiconductors, 38(3): p, 031002, DOI: 10.1088/1674-4926/38/3/031002.
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  • Dam, S., A. Thakur, A. G, and S. Hussain. 2019. Synthesis and characterisation of MoS2 thin films by electron beam evaporation, Thin Solid Films, 681: p, 78-85, DOI: 10.1016/j.tsf.2019.04.041.
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  • Cao, H., Z. Bai, Y. Li, Z. Xiao, X. Zhang, and G. Li. 2020. Solvothermal Synthesis of Defect-Rich Mixed 1T-2H MoS2 Nanoflowers for Enhanced Hydrodesulfurization, ACS Sustainable Chemistry & Engineering, 8(19): p, 7343-7352, DOI: 10.1021/acssuschemeng.0c00736.
  • Mishra, S., P.K. Maurya, and A.K. Mishra. 2020. 2H–MoS2 nanoflowers based high energy density solid state supercapacitor, Materials Chemistry and Physics, 255: p, 123551, DOI: 10.1016/j.matchemphys.2020.123551.
  • Qian, S., R. Yang, F. Lan, Y. Xu, K. Sun, S. Zhang, Y. Zhang, and Z. Dong. 2019. Growth of continuous MoS2 film with large grain size by chemical vapor deposition, Materials Science in Semiconductor Processing, 93: p, 317-323, DOI: 10.1016/j.mssp.2019.01.007.
  • Song, T.-s., L. Fu, N. Wan, J. Wu, and J. Xie. 2020. Hydrothermal synthesis of MoS2 nanoflowers for an efficient microbial electrosynthesis of acetate from CO2, Journal of CO2 Utilization, 41: p, 101231, DOI: 10.1016/j.jcou.2020.101231.
Toplam 59 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Araştırma Makalesi
Yazarlar

Burak Kıvrak 0000-0002-6785-7346

Mustafa Akyol 0000-0001-8584-0620

Yayımlanma Tarihi 17 Ocak 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 24 Sayı: 70

Kaynak Göster

APA Kıvrak, B., & Akyol, M. (2022). Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, 24(70), 81-90. https://doi.org/10.21205/deufmd.2022247009
AMA Kıvrak B, Akyol M. Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi. DEUFMD. Ocak 2022;24(70):81-90. doi:10.21205/deufmd.2022247009
Chicago Kıvrak, Burak, ve Mustafa Akyol. “Çözücü Ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi 24, sy. 70 (Ocak 2022): 81-90. https://doi.org/10.21205/deufmd.2022247009.
EndNote Kıvrak B, Akyol M (01 Ocak 2022) Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 24 70 81–90.
IEEE B. Kıvrak ve M. Akyol, “Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi”, DEUFMD, c. 24, sy. 70, ss. 81–90, 2022, doi: 10.21205/deufmd.2022247009.
ISNAD Kıvrak, Burak - Akyol, Mustafa. “Çözücü Ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 24/70 (Ocak 2022), 81-90. https://doi.org/10.21205/deufmd.2022247009.
JAMA Kıvrak B, Akyol M. Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi. DEUFMD. 2022;24:81–90.
MLA Kıvrak, Burak ve Mustafa Akyol. “Çözücü Ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, c. 24, sy. 70, 2022, ss. 81-90, doi:10.21205/deufmd.2022247009.
Vancouver Kıvrak B, Akyol M. Çözücü ve Isıl İşlem Sürecinin MoS2 İnce Filmlerinin Yapısal Özelliklerine Etkisinin İncelenmesi. DEUFMD. 2022;24(70):81-90.

Dokuz Eylül Üniversitesi, Mühendislik Fakültesi Dekanlığı Tınaztepe Yerleşkesi, Adatepe Mah. Doğuş Cad. No: 207-I / 35390 Buca-İZMİR.