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The Removal of Crystal Violet (CV) Dyestuff by Wheat Bran: Kinetic Studies

Yıl 2018, Cilt: 11 Sayı: 3, 435 - 450, 30.12.2018
https://doi.org/10.18185/erzifbed.414995

Öz

Kaynakça

  • Akar, T., Ozcan, A.S., Tunali,S., Ozcan, A. 2008. Biosorption of a Textile Dye (Acid Blue 40) by Cone Biomass of Thuja Orientalis: Estimation of Equilibrium, Thermodynamic and Kinetic Parameters. Bioresource Technology, 99(8), 3057–3065.
  • Albadarin, A.B., Solomon, S.,Kurniawan, T.A., Mangwandi, C., Walker, G. 2017. Single, Simultaneous and Consecutive Biosorption of Cr(VI) and Orange II onto Chemically Modified Masau Stones. Journal of Environmental Management, 204, 365–74.
  • Bentahar, S., Dbik, A., El Khomri, M., El Messaoudi, N., Lacherai, A. 2017. Adsorption of Methylene Blue , Crystal Violet and Congo Red from Binary and Ternary Systems with Natural Clay : Kinetic, Isotherm and Thermodynamic. Journal of Environmental Chemical Engineering, 5(6), 5921–5932.
  • Ceylan, Z., Mustafaoglu, D., Malkoc, E. 2017. Adsorption of Phenol by MMT-CTAB and WPT-CTAB : Equilibrium , Kinetic and Thermodynamic Study Adsorption of Phenol by MMT-CTAB and WPT-CTAB : Equilibrium, Kinetic and Thermodynamic Study. Particulate Science and Technology, 6351 (February), 1–11.
  • Dawood, S., Kanti Sen, T. 2012. Removal of Anionic Dye Congo Red from Aqueous Solution by Raw Pine and Acid-Treated Pine Cone Powder as Adsorbent: Equilibrium, Thermodynamic, Kinetics, Mechanism and Process Design. Water Research, 46(6), 1933–1946.
  • Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., Barka, N. 2015. Adsorption of Textile Dyes on Raw and Decanted Moroccan Clays: Kinetics, Equilibrium and Thermodynamics. Water Resources and Industry, 9, 16-29.
  • Ertugay, N. 2016. Basic Violet 10 (BV10) Removal from Aqueous Solutions Using Sawdust of Swietenia Mahagoni (Mahogany Trees): Adsorbent Characterization, Adsorption Isotherm, Kinetics, and Thermodynamic Studies. Desalination and Water Treatment, 57(26), 12335-12349.
  • Deniz, F. Şengül, K. 2015. Pinus Brutia Ten . (Kızılçam) Kozalak ve Yaprak Biyomasının Boya Biyosorpsiyon / Desorpsiyon Potansiyeli. KSÜ Doğa Bilimleri Dergisi, 17(3), 19-25.
  • Da Fontoura, J.T., Rolim, G.S., Mella, B., Farenzena, M., Gutterres, M. 2017. Defatted Microalgal Biomass as Biosorbent for the Removal of Acid Blue 161 Dye from Tannery Effluent. Journal of Environmental Chemical Engineering, 5(5), 5076–5084.
  • Guerrero-Coronilla, I., Morales-Barrera, L., Cristiani-Urbina, E. 2015. Kinetic, Isotherm and Thermodynamic Studies of Amaranth Dye Biosorption from Aqueous Solution onto Water Hyacinth Leaves. Journal of Environmental Management, 152, 99–108.
  • Khamparia, S., Jaspal, D. 2016. Adsorptive Removal of Direct Red 81 Dye from Aqueous Solution onto Argemone Mexicana. Sustainable Environment Research, 26(3), 117–123.
  • Kocaer, F. O., Alkan, U. 2002. Boyar Madde İçeren Teksti̇l Atıksularının Arıtım Alternati̇fleri̇. Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 7(1), 47–55.
  • Lawal, I.A., Chetty, D., Akpotu, S.O., Moodley, B. 2017. Sorption of Congo Red and Reactive Blue on Biomass and Activated Carbon Derived from Biomass Modified by Ionic Liquid. Environmental Nanotechnology, Monitoring and Management, 8(May), 83–91.
  • Liu, J., Wang, Z., Li, H., Hu, C., Raymer, P., Huang, Q. 2018. Effect of Solid State Fermentation of Peanut Shell on Its Dye Adsorption Performance. Bioresource Technology, 249 (October 2017), 307–314.
  • Mondal, N.K., Samanta, A., Dutta, S., Chattoraj, S. 2017.Optimization of Cr(VI) Biosorption onto Aspergillus Niger Using 3-Level Box-Behnken Design: Equilibrium, Kinetic, Thermodynamic and Regeneration Studies. Journal of Genetic Engineering and Biotechnology, 15(1), 151–160.
  • Mustafa, M.M., Jarnal, P., Alkhatip, M.F., Mahmod, S.S., Jimat, D.N., Ilyas, N.N. 2017. Panus Tigrinus as a Potential Biomass Source for Reactive Blue Decolorization: Isotherm and Kinetic Study. Electronic Journal of Biotechnology, 26, 7–11.
  • Ofomaja, A. E., Ho, Y.S. 2008. Effect of Temperatures and pH on Methyl Violet Biosorption by Mansonia Wood Sawdust. Bioresource Technology, 99(13), 5411–5417.
  • Oguntimein, G.B. 2015. ogunt. Journal of Environmental Chemical Engineering, 3(4), 2647–2661.
  • Köklü, R., Özer, Ç. 2018. Remazol Brillant Blue R (RBBR) Boyar maddesinin Düşük Maliyetli Bir Adsorban Olan Sigara Külü ile Giderimi Removal of Remazol Brilliant Blue R ( RBBR ) Dyes with a Low Cost Adsorbent , Cigarette Ash.Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(2), 174-180.
  • Rangabhashiyam, S., Lata, S. Balasubramanian P. 2017. Biosorption Characteristics of Methylene Blue and Malachite Green from Simulated Wastewater onto Carica Papaya Wood Biosorbent. Surfaces and Interfaces (September), 1–19.
  • Omer, O.S., Hussein, M.A., Hussein, B.H. M., Mgaidi, A. 2018. Adsorption Thermodynamics of Cationic Dyes (Methylene Blue and Crystal Violet) to a Natural Clay Mineral from Aqueous Solution between 293.15 and 323.15 K. Arabian Journal of Chemistry, 11, 615-623.
  • Salazar-Rabago, J.J., Leyva-Ramos, R., Rivera-Utrilla, J., Ocampo-Perez, R., Cerino-Cordova, F.J. 2017. Biosorption Mechanism of Methylene Blue from Aqueous Solution onto White Pine (Pinus Durangensis) Sawdust: Effect of Operating Conditions. Sustainable Environment Research, 27(1), 32–40.
  • Santos, S.C.R., Boaventura, R.A.R. 2016. Adsorption of Cationic and Anionic Azo Dyes on Sepiolite Clay: Equilibrium and Kinetic Studies in Batch Mode. Journal of Environmental Chemical Engineering, 4(2), 1473–1483.
  • Tang, H., Zhou, W., Zhang, L.2012. Adsorption Isotherms and Kinetics Studies of Malachite Green on Chitin Hydrogels. Journal of Hazardous Materials, 209–210, 218–225.
  • Wang, X. S., Liu, X., Wen, L., Zhou, Y., Jiang, Y., Li, Z. 2018. Comparison of Basic Dye Crystal Violet Removalfrom Aqueous Solution by Low-Cost Biosorbents. Separation Science and Technology, 43, 3712–3731.
  • Wang, K., Fu, J., Wang, S., Gao, M., Zhu, J., Wang, Z., Xu, Q. 2018.Polydopamine-Coated Magnetic Nanochains as Efficient Dye Adsorbent with Good Recyclability and Magnetic Separability. Journal of Colloid and Interface Science, 516, 263–273.
  • Yang, J.X., Hong, G.B. 2018. Adsorption Behavior of Modified Glossogyne Tenuifolia Leaves as a Potential Biosorbent for the Removal of Dyes. Journal of Molecular Liquids, 252, 289-295.
  • İmecik, Z., Dığrak, M., Halipçi, H.N. 2014. Safranin ‘in Sulu Ortamdan Platanus Orientalis L. Biyoması Kullanılarak Giderimi. Fırat Üniv. Fen Bilimleri Dergisi, 26(2), 139–145.
  • Zıba, C.A., Akarsu, S., Arslantaş, M., Dolaz, M. 2016. Tekstil Atık Sularında Renk Gidermede Kullanılan Koagulantlar : Nişasta ve CMPS’nin Floklaşmaya Etkisi. KSU. Journal of Engineering Sciences, 19(3), 110-114.

Buğday Kepeği Kullanılarak Crystal Violet (CV) Boyar Maddesinin Giderimi: Kinetik Çalışmalar

Yıl 2018, Cilt: 11 Sayı: 3, 435 - 450, 30.12.2018
https://doi.org/10.18185/erzifbed.414995

Öz

Boyar maddelerin yaygın
kullanımından kaynaklanan boyalı atık suların arıtılması önemli bir çevre
sorunudur. Bu nedenle boyar madde içeren tekstil endüstrisi atık sularından
renk giderim prosesleri ekolojik açıdan önem kazanmaktadır. Günümüzde büyük
hacimli atık sulardaki boyar maddelerin etkili ve ekonomik bir şekilde
giderilebilmesi için alternatif yöntemlere gereksinim vardır. Bu çalışmada
tekstil atık sularında yaygın olarak bulunan Crystal Violet (CV)’in buğday
kepeği üzerine adsorpsiyonu incelenmiştir. Kepeğin CV boyar maddesinin
adsorpsiyonu üzerinde etkilerini belirlemek için; farklı başlangıç boya
konsantrasyonları, pH değerleri, adsorbent konsantrasyonları ile sıcaklık
parametreleri denenmiş ve optimum koşullar sağlanmıştır. En yüksek giderimin
doğal pH (6.24)’da olduğu gözlemlenmiştir. Adsorbent miktarı belli bir değere
kadar arttıkça boyar madde giderimi de artmıştır. Ayrıca, adsorpsiyonun 120.
dakikada dengeye geldiği ve boyar madde konsantrasyonu arttıkça giderim
veriminin düştüğü görülmüştür. Bununla birlikte, sıcaklığın 25°C’den 45°C’ye
arttırılması boyar madde giderimini artırmıştır. Bunun yanında deneysel
verilerin Langmuir ve Freundlich izotermler ile yalancı birinci ve ikinci
derece kinetik modellere uygunluğu araştırılmıştır. Bu modellere ait
parametreler ile adsorpsiyon prosesine ait termodinamik parametreler
hesaplanmıştır. Karakterizasyon çalışmaları kapsamında buğday kepeği için
adsorpsiyon öncesi ve sonrası Fourier Transform Infrared (FTIR) ve Scanning
Electron Microscopy (SEM) analizi yapılarak biyosorpsiyon mekanizmasındaki
fonksiyonel gruplar incelenmiş ve biyosorpsiyon sonrası oluşan yapısal
değişikliklerin varlığı görülmüştür.

Kaynakça

  • Akar, T., Ozcan, A.S., Tunali,S., Ozcan, A. 2008. Biosorption of a Textile Dye (Acid Blue 40) by Cone Biomass of Thuja Orientalis: Estimation of Equilibrium, Thermodynamic and Kinetic Parameters. Bioresource Technology, 99(8), 3057–3065.
  • Albadarin, A.B., Solomon, S.,Kurniawan, T.A., Mangwandi, C., Walker, G. 2017. Single, Simultaneous and Consecutive Biosorption of Cr(VI) and Orange II onto Chemically Modified Masau Stones. Journal of Environmental Management, 204, 365–74.
  • Bentahar, S., Dbik, A., El Khomri, M., El Messaoudi, N., Lacherai, A. 2017. Adsorption of Methylene Blue , Crystal Violet and Congo Red from Binary and Ternary Systems with Natural Clay : Kinetic, Isotherm and Thermodynamic. Journal of Environmental Chemical Engineering, 5(6), 5921–5932.
  • Ceylan, Z., Mustafaoglu, D., Malkoc, E. 2017. Adsorption of Phenol by MMT-CTAB and WPT-CTAB : Equilibrium , Kinetic and Thermodynamic Study Adsorption of Phenol by MMT-CTAB and WPT-CTAB : Equilibrium, Kinetic and Thermodynamic Study. Particulate Science and Technology, 6351 (February), 1–11.
  • Dawood, S., Kanti Sen, T. 2012. Removal of Anionic Dye Congo Red from Aqueous Solution by Raw Pine and Acid-Treated Pine Cone Powder as Adsorbent: Equilibrium, Thermodynamic, Kinetics, Mechanism and Process Design. Water Research, 46(6), 1933–1946.
  • Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., Barka, N. 2015. Adsorption of Textile Dyes on Raw and Decanted Moroccan Clays: Kinetics, Equilibrium and Thermodynamics. Water Resources and Industry, 9, 16-29.
  • Ertugay, N. 2016. Basic Violet 10 (BV10) Removal from Aqueous Solutions Using Sawdust of Swietenia Mahagoni (Mahogany Trees): Adsorbent Characterization, Adsorption Isotherm, Kinetics, and Thermodynamic Studies. Desalination and Water Treatment, 57(26), 12335-12349.
  • Deniz, F. Şengül, K. 2015. Pinus Brutia Ten . (Kızılçam) Kozalak ve Yaprak Biyomasının Boya Biyosorpsiyon / Desorpsiyon Potansiyeli. KSÜ Doğa Bilimleri Dergisi, 17(3), 19-25.
  • Da Fontoura, J.T., Rolim, G.S., Mella, B., Farenzena, M., Gutterres, M. 2017. Defatted Microalgal Biomass as Biosorbent for the Removal of Acid Blue 161 Dye from Tannery Effluent. Journal of Environmental Chemical Engineering, 5(5), 5076–5084.
  • Guerrero-Coronilla, I., Morales-Barrera, L., Cristiani-Urbina, E. 2015. Kinetic, Isotherm and Thermodynamic Studies of Amaranth Dye Biosorption from Aqueous Solution onto Water Hyacinth Leaves. Journal of Environmental Management, 152, 99–108.
  • Khamparia, S., Jaspal, D. 2016. Adsorptive Removal of Direct Red 81 Dye from Aqueous Solution onto Argemone Mexicana. Sustainable Environment Research, 26(3), 117–123.
  • Kocaer, F. O., Alkan, U. 2002. Boyar Madde İçeren Teksti̇l Atıksularının Arıtım Alternati̇fleri̇. Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 7(1), 47–55.
  • Lawal, I.A., Chetty, D., Akpotu, S.O., Moodley, B. 2017. Sorption of Congo Red and Reactive Blue on Biomass and Activated Carbon Derived from Biomass Modified by Ionic Liquid. Environmental Nanotechnology, Monitoring and Management, 8(May), 83–91.
  • Liu, J., Wang, Z., Li, H., Hu, C., Raymer, P., Huang, Q. 2018. Effect of Solid State Fermentation of Peanut Shell on Its Dye Adsorption Performance. Bioresource Technology, 249 (October 2017), 307–314.
  • Mondal, N.K., Samanta, A., Dutta, S., Chattoraj, S. 2017.Optimization of Cr(VI) Biosorption onto Aspergillus Niger Using 3-Level Box-Behnken Design: Equilibrium, Kinetic, Thermodynamic and Regeneration Studies. Journal of Genetic Engineering and Biotechnology, 15(1), 151–160.
  • Mustafa, M.M., Jarnal, P., Alkhatip, M.F., Mahmod, S.S., Jimat, D.N., Ilyas, N.N. 2017. Panus Tigrinus as a Potential Biomass Source for Reactive Blue Decolorization: Isotherm and Kinetic Study. Electronic Journal of Biotechnology, 26, 7–11.
  • Ofomaja, A. E., Ho, Y.S. 2008. Effect of Temperatures and pH on Methyl Violet Biosorption by Mansonia Wood Sawdust. Bioresource Technology, 99(13), 5411–5417.
  • Oguntimein, G.B. 2015. ogunt. Journal of Environmental Chemical Engineering, 3(4), 2647–2661.
  • Köklü, R., Özer, Ç. 2018. Remazol Brillant Blue R (RBBR) Boyar maddesinin Düşük Maliyetli Bir Adsorban Olan Sigara Külü ile Giderimi Removal of Remazol Brilliant Blue R ( RBBR ) Dyes with a Low Cost Adsorbent , Cigarette Ash.Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(2), 174-180.
  • Rangabhashiyam, S., Lata, S. Balasubramanian P. 2017. Biosorption Characteristics of Methylene Blue and Malachite Green from Simulated Wastewater onto Carica Papaya Wood Biosorbent. Surfaces and Interfaces (September), 1–19.
  • Omer, O.S., Hussein, M.A., Hussein, B.H. M., Mgaidi, A. 2018. Adsorption Thermodynamics of Cationic Dyes (Methylene Blue and Crystal Violet) to a Natural Clay Mineral from Aqueous Solution between 293.15 and 323.15 K. Arabian Journal of Chemistry, 11, 615-623.
  • Salazar-Rabago, J.J., Leyva-Ramos, R., Rivera-Utrilla, J., Ocampo-Perez, R., Cerino-Cordova, F.J. 2017. Biosorption Mechanism of Methylene Blue from Aqueous Solution onto White Pine (Pinus Durangensis) Sawdust: Effect of Operating Conditions. Sustainable Environment Research, 27(1), 32–40.
  • Santos, S.C.R., Boaventura, R.A.R. 2016. Adsorption of Cationic and Anionic Azo Dyes on Sepiolite Clay: Equilibrium and Kinetic Studies in Batch Mode. Journal of Environmental Chemical Engineering, 4(2), 1473–1483.
  • Tang, H., Zhou, W., Zhang, L.2012. Adsorption Isotherms and Kinetics Studies of Malachite Green on Chitin Hydrogels. Journal of Hazardous Materials, 209–210, 218–225.
  • Wang, X. S., Liu, X., Wen, L., Zhou, Y., Jiang, Y., Li, Z. 2018. Comparison of Basic Dye Crystal Violet Removalfrom Aqueous Solution by Low-Cost Biosorbents. Separation Science and Technology, 43, 3712–3731.
  • Wang, K., Fu, J., Wang, S., Gao, M., Zhu, J., Wang, Z., Xu, Q. 2018.Polydopamine-Coated Magnetic Nanochains as Efficient Dye Adsorbent with Good Recyclability and Magnetic Separability. Journal of Colloid and Interface Science, 516, 263–273.
  • Yang, J.X., Hong, G.B. 2018. Adsorption Behavior of Modified Glossogyne Tenuifolia Leaves as a Potential Biosorbent for the Removal of Dyes. Journal of Molecular Liquids, 252, 289-295.
  • İmecik, Z., Dığrak, M., Halipçi, H.N. 2014. Safranin ‘in Sulu Ortamdan Platanus Orientalis L. Biyoması Kullanılarak Giderimi. Fırat Üniv. Fen Bilimleri Dergisi, 26(2), 139–145.
  • Zıba, C.A., Akarsu, S., Arslantaş, M., Dolaz, M. 2016. Tekstil Atık Sularında Renk Gidermede Kullanılan Koagulantlar : Nişasta ve CMPS’nin Floklaşmaya Etkisi. KSU. Journal of Engineering Sciences, 19(3), 110-114.
Toplam 29 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Neşe Ertugay

Yayımlanma Tarihi 30 Aralık 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 11 Sayı: 3

Kaynak Göster

APA Ertugay, N. (2018). Buğday Kepeği Kullanılarak Crystal Violet (CV) Boyar Maddesinin Giderimi: Kinetik Çalışmalar. Erzincan University Journal of Science and Technology, 11(3), 435-450. https://doi.org/10.18185/erzifbed.414995