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Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı

Yıl 2021, Cilt: 27 Sayı: 7, 873 - 881, 31.12.2021

Çiğdem Er Çalışkan Harun Çiftçi

Öz

Kağıt fabrikası çamur atığının (KFÇA) farklı sıcaklıklarda iki sa. süre ile karbonizasyonundan elde edilen karbonizasyon (KFÇAK) ürünü ile sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunun incelendiği bu çalışmada, karbonizasyon sıcaklığının artmasıyla adsorpsiyon veriminin arttığı gözlenmiştir. Cd(II) iyonlarının adsorpsiyon verimi büyük ölçüde ortamın pH’sına bağlıdır. 100 mg/L’lik Cd(II) çözeltisinin 5 g/L dozunda 300, 400 ve 500 °C’deki karbonizasyon ürünü ile 240 dk. süre ile pH 5.5’da temas ettirilmesiyle mevcut Cd(II) iyonlarının sırasıyla %45.3, %52.4 ve %61’i giderilmiştir. Bu değerler Cd(II) iyonlarının başlangıç konsantrasyonu 50 mg/L olarak alındığında %56, %65.3 ve %73.4’e yükselmiştir. 100 mg/L’lik başlangıç konsantrasyonu için doz 20 g/L olarak uygulandığında ise mevcut Cd(II) iyonlarının tamamı (300 °C’deki karbonizasyon ürünü hariç) adsorplanmıştır. Her karbonizasyon ürünü için elde edilen sonuçlar Langmuir ve Freundlich izotermlerine uygulanmıştır. Kadmiyum adsorpsiyon kinetiği, ikinci dereceden bir model ile tanımlandı ve kadmiyum adsorpsiyon izotermi, Langmuir modeline daha iyi uyduğu belirlendi. Sonuçların izoterm denklemlerine uygulanabilirliği ve izoterm sabitlerinin değerinin karbonizasyon sıcaklığına bağlı olarak değişimleri irdelenmiştir.

Anahtar Kelimeler

Kâğıt fabrikası çamur atığı Adsorpsiyon Aktif karbon Karbonizasyon Cd(II) giderimi

Kaynakça

  • [1] Iqbal M, Iqbal N, Bhatti IA, Ahmad N, Zahid M. “Response surface methodology application in optimization of cadmium adsorption by shoe waste: A good option of waste mitigation by waste”. Ecological Engineering, 88, 265-275, 2016.
  • [2] Wen Y, Ji Y, Zhang S, Zhang J, Cai G. “A simple low-cost method to prepare lignocellulose-based composites for efficient removal of Cd (II) from wastewater”. Polymers, 2019. https://doi.org/10.3390/polym11040711
  • [3] Petrella A, Spasiano D, Acquafredda P, De Vietro N, Ranieri E, Cosma P, Petruzzelli D. “Heavy metals retention (Pb (II), Cd (II), Ni (II)) from single and multimetal solutions by natural biosorbents from the olive oil milling operations”. Process Safety and Environmental Protection, 114, 79-90, 2018.
  • [4] Asuquo ED, & Martin AD. “Sorption of cadmium (II) ion from aqueous solution onto sweet potato (Ipomoea batatas L.) peel adsorbent: characterisation, kinetic and isotherm studies”. Journal of Environmental Chemical Engineering, 4(4), 4207-4228, 2016.
  • [5] Correa ML, Velasquez JA, Quintana GC. “Uncommon crop residues as Ni (II) and Cd (II) biosorbents”. Industrial & Engineering Chemistry Research, 51(38), 12456-12462, 2012.
  • [6] Demirbas A. “Adsorption of lead and cadmium ions in aqueous solutions onto modified lignin from alkali glycerol delignication”. Journal of Hazardous Materials, 109(1-3), 221-226, 2004.
  • [7] Boota R, Bhatti HN, Hanif M. A. “Removal of Cu (II) and Zn (II) using lignocellulosic fiber derived from Citrus reticulata (Kinnow) waste biomass”. Separation Science and Technology, 44(16), 4000-4022, 2009.
  • [8] Wilson K, Yang H, Seo CW, Marshall WE. “Select metal adsorption by activated carbon made from peanut shells”. Bioresource Technology, 97(18), 2266-2270, 2006.
  • [9] Nagy B, Manzatu C, Toeroek A, Indolean C, MA, Tonk S, Majdik C. “Isotherm and thermodynamic studies of Cd (II) removal process using chemically modified lignocellulosic adsorbent”. Rev Roum Chim, 60(2-3), 257-264, 2015.
  • [10] Tang X, Wang H, Hou M, Song L, Zhou C, Zhao H, Shi L. “Highly efficient adsorption of cadmium (II) onto durable coconut fiber residue”. Desalination and Water Treatment, 57(32), 15098-15107, 2016.
  • [11] Wan S, Ma Z, Xue Y, Ma M, Xu S, Qian L, Zhang Q. “Sorption of lead (II), cadmium (II), and copper (II) ions from aqueous solutions using tea waste”. Industrial & Engineering Chemistry Research, 53(9), 3629-3635, 2014.
  • [12] Zheng L, Dang Z, Yi X, Zhang H. “Equilibrium and kinetic studies of adsorption of Cd (II) from aqueous solution using modified corn stalk”. Journal of Hazardous Materials, 176(1-3), 650-656, 2010.
  • [13] El-Sayed GO, Dessouki HA, Ibrahim, SS. “Biosorption of Ni (II) and Cd (II) ions from aqueous solutions onto rice straw”. Chemical Sciences Journal, 2010(9), 1-11, 2010.
  • [14] Arslanoğlu H. "Direct and facile synthesis of highly porous low cost carbon from potassium-rich wine stone and their application for high-performance removal". Journal of Hazardous Materials, 374, 238-247, 2019.
  • [15] Demirbas A. “Heavy metal adsorption onto agro-based waste materials: a review”. Journal of Hazardous Materials, 157(2-3), 220-229, 2008.
  • [16] Monte MC, Fuente E, Blanco A, Negro C. “Waste management from pulp and paper production in the European Union”. Waste Management, 29(1), 293-308, 2009.
  • [17] Ahmaruzzaman M. “Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals”. Advances in Colloid and Interface Science, 166(1), 36-59, 2011.
  • [18] Gavrilescu D. “Energy from biomass in pulp and paper mills”. Environmental Engineering and Management Journal, 7(5), 537-546, 2008.
  • [19] He X, Yao L, Lian, Z, Ni J. “Paper sludge as a feasible soil amendment for the immobilization of Pb2+”. Journal of Environmental Sciences, 22(3), 413-420, 2010.
  • [20] González PG, Pliego-Cuervo YB. “Adsorption of Cd (II), Hg (II) and Zn (II) from aqueous solution using mesoporous activated carbon produced from Bambusa vulgaris striata”. Chemical Engineering Research and Design, 92(11), 2715-2724, 2014.
  • [21] Li Q, Chai L, Qin W. “Cadmium (II) adsorption on esterified spent grain: equilibrium modeling and possible mechanisms”. Chemical Engineering Journal, 197, 173-180, 2012.
  • [22] Asuquo ED, Martin AD, Nzerem P. “Evaluation of Cd (II) ion removal from aqueous solution by a low-cost adsorbent prepared from white yam (Dioscorea rotundata) waste using batch sorption”. Chem. Engineering, 2018. https://doi.org/10.3390/chemengineering2030035.
  • [23] Arslanoğlu H, Kaya S, Tümen F. "Cr (VI) adsorption on lowcost activated carbon developed from grape marc-vinasse mixture". Particulate Science and Technology, 38(6), 768-781, 2020.
  • [24] Yaras A, Arslanoğlu H. "Valorization of paper mill sludge as adsorbent in adsorption process of copper (II) ion from synthetic solution: kinetic, isotherm and thermodynamic studies”. Arabian Journal for Science and Engineering, 43(5), 2393-2402, 2018.
  • [25] Eren MŞ, Arslanoğlu H, Çiftçi H. “Production of microporous Cu-doped BTC (Cu-BTC) metal-organic framework composite materials, superior adsorbents for the removal of methylene blue (Basic Blue 9)”. Journal of Environmental Chemical Engineering, 2020. https://doi.org/10.1016/j.jece.2020.104247.
  • [26] Arslanoğlu H, Orhan R, Turan MD. "Application of response surface methodology for the optimization of copper removal from aqueous solution by activated carbon prepared using waste polyurethane”. Analytical Letters, 53(9), 1343-1365, 2020.
  • [27] Gupta VK, Nayak A. “Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles”. Chemical Engineering Journal, 180, 81-90, 2012.
  • [28] Min SH, Han JS, Shin EW, Park JK. “Improvement of cadmium ion removal by base treatment of juniper fiber”. Water Research, 38(5), 1289-1295, 2004.
  • [29] Fiol N, Villaescusa I, Martínez M, Miralles N, Poch J, Serarols J. “Sorption of Pb (II), Ni (II), Cu (II) and Cd (II) from aqueous solution by olive stone waste”. Separation and Purification Technology, 50(1), 132-140, 2006.
  • [30] Al-Qahtani KM. “Water purification using different waste fruit cortexes for the removal of heavy metals”. Journal of Taibah University for Science, 10(5), 700-708, 2016.
  • [31] Tounsadi H, Khalidi A, Abdennouri M, Barka N. “Biosorption potential of Diplotaxis harra and Glebionis coronaria L. biomasses for the removal of Cd (II) and Co (II) from aqueous solutions”. Journal of Environmental Chemical Engineering, 3(2), 822-830, 2015.
  • [32] Taty-Costodes VC, Fauduet H, Porte C, Delacroix A. “Removal of Cd (II) and Pb (II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris”. Journal of Hazardous Materials, 105(1-3), 121-142, 2003.
  • [33] Vázquez G, Freire MS, González-Alvarez J, Antorrena G. “Equilibrium and kinetic modelling of the adsorption of Cd2+ ions onto chestnut shell”. Desalination, 249(2), 855-860, 2009.
  • [34] Saeed A, Akhter MW, Iqbal M. “Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent”. Separation and Purification Technology, 45(1), 25-31, 2005.
  • [35] Izanlou H, Naseri S. “Cadmium removal from aqueous solutions by ground pin cone”. Iranian Journal of Environmental Health Science and Engineering, 2(1), 33-42, 2005.

The use of carbon obtained by carbonization of paper mill sludge waste in the adsorption of Cd(II) ions from aqueous solutions

Yıl 2021, Cilt: 27 Sayı: 7, 873 - 881, 31.12.2021

Çiğdem Er Çalışkan Harun Çiftçi

Öz

In this study, in which the adsorption of 𝐶𝑑(𝐼𝐼) ions from aqueous solutions with the carbonization product obtained from the carbonization of paper mill waste sludge at different temperatures for two hours, it was observed that the adsorption efficiency increased with the increase of the carbonization temperature. The adsorption efficiency of 𝐶𝑑(𝐼𝐼) ions depends largely on the pH of the environment. By contacting the 100 𝑚𝑔/𝐿 solution of 𝐶𝑑(𝐼𝐼) with the carbonization product at 300, 400 𝑎𝑛𝑑 500 °𝐶 at a dose of 5 𝑔/𝐿 for 240 𝑚𝑖𝑛 at 𝑝𝐻 5.5, the current 𝐶𝑑(𝐼𝐼) ions were 45.3%, 52.4% and 61% removed. These values increased to 56%, 65.3% and 73.4% when the initial concentration of 𝐶𝑑(𝐼𝐼) ions was taken as 50 𝑚𝑔/𝐿. When the dose was applied as 20 g/L for the initial concentration of 100 𝑚𝑔/𝐿, all of the existing Cd (II) ions (except the carbonization product at 300 °C) were adsorbed. The results obtained for each carbonization product were applied to the Langmuir and Freundlich isotherms. The cadmium adsorption kinetics were defined with a second order model and the cadmium adsorption isotherm was determined to fit the Langmuir model better. The applicability of the results to the isotherm equations and the changes in the value of the isotherm constants depending on the carbonization temperature were examined.

Anahtar Kelimeler

Paper mill sludge waste Adsorption Activated carbon Carbonization Cd (II) removal

Kaynakça

  • [1] Iqbal M, Iqbal N, Bhatti IA, Ahmad N, Zahid M. “Response surface methodology application in optimization of cadmium adsorption by shoe waste: A good option of waste mitigation by waste”. Ecological Engineering, 88, 265-275, 2016.
  • [2] Wen Y, Ji Y, Zhang S, Zhang J, Cai G. “A simple low-cost method to prepare lignocellulose-based composites for efficient removal of Cd (II) from wastewater”. Polymers, 2019. https://doi.org/10.3390/polym11040711
  • [3] Petrella A, Spasiano D, Acquafredda P, De Vietro N, Ranieri E, Cosma P, Petruzzelli D. “Heavy metals retention (Pb (II), Cd (II), Ni (II)) from single and multimetal solutions by natural biosorbents from the olive oil milling operations”. Process Safety and Environmental Protection, 114, 79-90, 2018.
  • [4] Asuquo ED, & Martin AD. “Sorption of cadmium (II) ion from aqueous solution onto sweet potato (Ipomoea batatas L.) peel adsorbent: characterisation, kinetic and isotherm studies”. Journal of Environmental Chemical Engineering, 4(4), 4207-4228, 2016.
  • [5] Correa ML, Velasquez JA, Quintana GC. “Uncommon crop residues as Ni (II) and Cd (II) biosorbents”. Industrial & Engineering Chemistry Research, 51(38), 12456-12462, 2012.
  • [6] Demirbas A. “Adsorption of lead and cadmium ions in aqueous solutions onto modified lignin from alkali glycerol delignication”. Journal of Hazardous Materials, 109(1-3), 221-226, 2004.
  • [7] Boota R, Bhatti HN, Hanif M. A. “Removal of Cu (II) and Zn (II) using lignocellulosic fiber derived from Citrus reticulata (Kinnow) waste biomass”. Separation Science and Technology, 44(16), 4000-4022, 2009.
  • [8] Wilson K, Yang H, Seo CW, Marshall WE. “Select metal adsorption by activated carbon made from peanut shells”. Bioresource Technology, 97(18), 2266-2270, 2006.
  • [9] Nagy B, Manzatu C, Toeroek A, Indolean C, MA, Tonk S, Majdik C. “Isotherm and thermodynamic studies of Cd (II) removal process using chemically modified lignocellulosic adsorbent”. Rev Roum Chim, 60(2-3), 257-264, 2015.
  • [10] Tang X, Wang H, Hou M, Song L, Zhou C, Zhao H, Shi L. “Highly efficient adsorption of cadmium (II) onto durable coconut fiber residue”. Desalination and Water Treatment, 57(32), 15098-15107, 2016.
  • [11] Wan S, Ma Z, Xue Y, Ma M, Xu S, Qian L, Zhang Q. “Sorption of lead (II), cadmium (II), and copper (II) ions from aqueous solutions using tea waste”. Industrial & Engineering Chemistry Research, 53(9), 3629-3635, 2014.
  • [12] Zheng L, Dang Z, Yi X, Zhang H. “Equilibrium and kinetic studies of adsorption of Cd (II) from aqueous solution using modified corn stalk”. Journal of Hazardous Materials, 176(1-3), 650-656, 2010.
  • [13] El-Sayed GO, Dessouki HA, Ibrahim, SS. “Biosorption of Ni (II) and Cd (II) ions from aqueous solutions onto rice straw”. Chemical Sciences Journal, 2010(9), 1-11, 2010.
  • [14] Arslanoğlu H. "Direct and facile synthesis of highly porous low cost carbon from potassium-rich wine stone and their application for high-performance removal". Journal of Hazardous Materials, 374, 238-247, 2019.
  • [15] Demirbas A. “Heavy metal adsorption onto agro-based waste materials: a review”. Journal of Hazardous Materials, 157(2-3), 220-229, 2008.
  • [16] Monte MC, Fuente E, Blanco A, Negro C. “Waste management from pulp and paper production in the European Union”. Waste Management, 29(1), 293-308, 2009.
  • [17] Ahmaruzzaman M. “Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals”. Advances in Colloid and Interface Science, 166(1), 36-59, 2011.
  • [18] Gavrilescu D. “Energy from biomass in pulp and paper mills”. Environmental Engineering and Management Journal, 7(5), 537-546, 2008.
  • [19] He X, Yao L, Lian, Z, Ni J. “Paper sludge as a feasible soil amendment for the immobilization of Pb2+”. Journal of Environmental Sciences, 22(3), 413-420, 2010.
  • [20] González PG, Pliego-Cuervo YB. “Adsorption of Cd (II), Hg (II) and Zn (II) from aqueous solution using mesoporous activated carbon produced from Bambusa vulgaris striata”. Chemical Engineering Research and Design, 92(11), 2715-2724, 2014.
  • [21] Li Q, Chai L, Qin W. “Cadmium (II) adsorption on esterified spent grain: equilibrium modeling and possible mechanisms”. Chemical Engineering Journal, 197, 173-180, 2012.
  • [22] Asuquo ED, Martin AD, Nzerem P. “Evaluation of Cd (II) ion removal from aqueous solution by a low-cost adsorbent prepared from white yam (Dioscorea rotundata) waste using batch sorption”. Chem. Engineering, 2018. https://doi.org/10.3390/chemengineering2030035.
  • [23] Arslanoğlu H, Kaya S, Tümen F. "Cr (VI) adsorption on lowcost activated carbon developed from grape marc-vinasse mixture". Particulate Science and Technology, 38(6), 768-781, 2020.
  • [24] Yaras A, Arslanoğlu H. "Valorization of paper mill sludge as adsorbent in adsorption process of copper (II) ion from synthetic solution: kinetic, isotherm and thermodynamic studies”. Arabian Journal for Science and Engineering, 43(5), 2393-2402, 2018.
  • [25] Eren MŞ, Arslanoğlu H, Çiftçi H. “Production of microporous Cu-doped BTC (Cu-BTC) metal-organic framework composite materials, superior adsorbents for the removal of methylene blue (Basic Blue 9)”. Journal of Environmental Chemical Engineering, 2020. https://doi.org/10.1016/j.jece.2020.104247.
  • [26] Arslanoğlu H, Orhan R, Turan MD. "Application of response surface methodology for the optimization of copper removal from aqueous solution by activated carbon prepared using waste polyurethane”. Analytical Letters, 53(9), 1343-1365, 2020.
  • [27] Gupta VK, Nayak A. “Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles”. Chemical Engineering Journal, 180, 81-90, 2012.
  • [28] Min SH, Han JS, Shin EW, Park JK. “Improvement of cadmium ion removal by base treatment of juniper fiber”. Water Research, 38(5), 1289-1295, 2004.
  • [29] Fiol N, Villaescusa I, Martínez M, Miralles N, Poch J, Serarols J. “Sorption of Pb (II), Ni (II), Cu (II) and Cd (II) from aqueous solution by olive stone waste”. Separation and Purification Technology, 50(1), 132-140, 2006.
  • [30] Al-Qahtani KM. “Water purification using different waste fruit cortexes for the removal of heavy metals”. Journal of Taibah University for Science, 10(5), 700-708, 2016.
  • [31] Tounsadi H, Khalidi A, Abdennouri M, Barka N. “Biosorption potential of Diplotaxis harra and Glebionis coronaria L. biomasses for the removal of Cd (II) and Co (II) from aqueous solutions”. Journal of Environmental Chemical Engineering, 3(2), 822-830, 2015.
  • [32] Taty-Costodes VC, Fauduet H, Porte C, Delacroix A. “Removal of Cd (II) and Pb (II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris”. Journal of Hazardous Materials, 105(1-3), 121-142, 2003.
  • [33] Vázquez G, Freire MS, González-Alvarez J, Antorrena G. “Equilibrium and kinetic modelling of the adsorption of Cd2+ ions onto chestnut shell”. Desalination, 249(2), 855-860, 2009.
  • [34] Saeed A, Akhter MW, Iqbal M. “Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent”. Separation and Purification Technology, 45(1), 25-31, 2005.
  • [35] Izanlou H, Naseri S. “Cadmium removal from aqueous solutions by ground pin cone”. Iranian Journal of Environmental Health Science and Engineering, 2(1), 33-42, 2005.
Toplam 35 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Kimya Müh. / Tekstil Müh. / Gıda Müh.
Yazarlar

Çiğdem Er Çalışkan

Harun Çiftçi Bu kişi benim

Yayımlanma Tarihi 31 Aralık 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 27 Sayı: 7

Kaynak Göster

APA Er Çalışkan, Ç., & Çiftçi, H. (2021). Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 27(7), 873-881.
AMA Er Çalışkan Ç, Çiftçi H. Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Aralık 2021;27(7):873-881.
Chicago Er Çalışkan, Çiğdem, ve Harun Çiftçi. “Sulu çözeltilerden Cd(II) iyonlarının Adsorpsiyonunda kağıt Fabrikası çamur atığının Karbonizasyonu Ile Elde Edilen Karbonun kullanımı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 27, sy. 7 (Aralık 2021): 873-81.
EndNote Er Çalışkan Ç, Çiftçi H (01 Aralık 2021) Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 27 7 873–881.
IEEE Ç. Er Çalışkan ve H. Çiftçi, “Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 27, sy. 7, ss. 873–881, 2021.
ISNAD Er Çalışkan, Çiğdem - Çiftçi, Harun. “Sulu çözeltilerden Cd(II) iyonlarının Adsorpsiyonunda kağıt Fabrikası çamur atığının Karbonizasyonu Ile Elde Edilen Karbonun kullanımı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 27/7 (Aralık 2021), 873-881.
JAMA Er Çalışkan Ç, Çiftçi H. Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2021;27:873–881.
MLA Er Çalışkan, Çiğdem ve Harun Çiftçi. “Sulu çözeltilerden Cd(II) iyonlarının Adsorpsiyonunda kağıt Fabrikası çamur atığının Karbonizasyonu Ile Elde Edilen Karbonun kullanımı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 27, sy. 7, 2021, ss. 873-81.
Vancouver Er Çalışkan Ç, Çiftçi H. Sulu çözeltilerden Cd(II) iyonlarının adsorpsiyonunda kağıt fabrikası çamur atığının karbonizasyonu ile elde edilen karbonun kullanımı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2021;27(7):873-81.





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