Determination and Comparison of Macro, Trace and Toxic Element Content of Some Roughages by ICP OES Technique

Mehmet Düzgün; Şerif Kahraman

doi:10.18016/ksutarimdoga.vi.1544769

EN TR

Determination and Comparison of Macro, Trace and Toxic Element Content of Some Roughages by ICP OES Technique

Abstract

It is critical to determine the amount of mineral and toxic elements in roughages, which play an important role in animal nutrition. In this study, macro (Ca, K, Na, Mg, P), trace (Fe, Mn, Zn, Cu, Ni, Co, Cr, Sn, V, Si, Se, Sr, Sb, B), and toxic element (Al, As, Be, Cd, Pb) analysis of 14 roughages were determined by the Inductively Coupled Plasma Optik Emission Spectrometry (ICP OES) method. CRM (NCS DC 73350, poplar leaves) confirmed the accuracy of the method. The samples were solubilized according to the microwave wet digestion method. The macro, trace and toxic element contents of 14 roughages were compared and evaluated according to the results of the analyses. Furthermore, the hierarchical clustering analysis (HCA) displayed the groups as dendrograms. Toxic elements like As, Be, Cd, Co, and Sb were not found in any of the samples. The only one that was found was Pb, which was 0.181±0.12, 0.45+0.07, and 0.40+0.13 mg kg-1 in grain corn leaf, sorghum leaf, and lentil straw, in that order. On the other hand, Sn was found as 0.01+0.005 mg kg-1 only in fodder pea stalk and Si was identified as 1015+140 mg kg-1 only in chickpea straw. In the study, it can be suggested that different roughages contain macro and trace elements at varying rates, and these roughages can be included in the rations according to these element ratios.

Keywords

Bazı Kaba Yemlerin Makro, İz ve Toksik Element İçeriklerinin ICP OES Tekniği Kullanılarak Belirlenmesi ve Karşılaştırılması

Öz

Ruminant hayvanların beslenmesinde önemli bir yere sahip olan kaba yemlerde mineral ve toksik elementlerin miktarının belirlenmesi oldukça önemlidir. Bu çalışmada, 14 kaba yemin makro (Ca, K, Na, Mg, P), iz (Fe, Mn, Zn, Cu, Ni, Co, Cr, Sn, V, Si, Se, Sr, Sb ve B) ve toksik element (Al, As, Be, Cd, Pb) miktarları İndüktif Eşleşmiş Plazma Optik Emisyon Spektrometresi (ICP OES) yöntemi ile belirlenmiştir. Yöntemin doğruluğu CRM (NCS DC 73350, kavak yaprakları) ile teyit edilmiştir. Örnekler mikrodalga yaş yakma yöntemine göre çözündürülmüştür. Analiz sonuçları çerçevesinde 14 kaba yemin makro, iz ve toksik element içerikleri karşılaştırılmış ve değerlendirilmiştir. Ayrıca, hiyerarşik kümeleme analizi (HCA) ile gruplar dendogram olarak gösterilmiştir. Çalışma sonucunda, tane mısır yaprağı, sorgum yaprağı ve mercimek samanında sırasıyla 0,181±0,12, 0,45+0,07, 0,40+0,13 mg kg-1 Pb tespit edilirken, toksik elementler (As, Be, Cd, Co ve Sb) hiçbir örnekte tespit edilmemiştir. Öte yandan, Sn sadece yem bezelyesi sapında (0.01+0.005 mg kg-1) ve Si sadece nohut samanında (1015+140 mg kg-1) tespit edilmiştir. Çalışmada farklı kaba yemlerin değişen oranlarda makro ve eser element ihtiva ettiği ve bu kaba yemlerin içerdikleri bu element oranlarına göre rasyonlara dahil edilebileceği önerisi yapılabilir.

Anahtar Kelimeler

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Details

Primary Language

English

Subjects

Botany (Other) , Animal Diet and Nutrition , Pasture-Meadow Forage Plants

Journal Section

Research Article

Authors

Mehmet Düzgün ^*
0000-0003-4269-5544
Türkiye

Şerif Kahraman
0000-0003-1160-0792
Türkiye

Early Pub Date

March 20, 2025

Publication Date

March 27, 2025

Submission Date

September 6, 2024

Acceptance Date

February 7, 2025

Published in Issue

Year 2025 Volume: 28 Number: 2

DOI

https://doi.org/10.18016/ksutarimdoga.vi.1544769

IZ

https://izlik.org/JA69KS45ZE

Cite

RIS / Bibtex

APA

Düzgün, M., & Kahraman, Ş. (2025). Determination and Comparison of Macro, Trace and Toxic Element Content of Some Roughages by ICP OES Technique. Kahramanmaraş Sütçü İmam Üniversitesi Tarım Ve Doğa Dergisi, 28(2), 580-592. https://doi.org/10.18016/ksutarimdoga.vi.1544769

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